In contrast to Lewis-acid catalysts, Brønsted acids have been employed primarily as
catalysts for the formation and cleavage of C− O bonds, such as hydrolysis and formation of …

Since the groundbreaking reports by the groups of Akiyama and Terada on the use of BINOL-
derived phosphoric acids as organocatalysts, 1, 2 the area of enantioselective Brønsted acid …

The development of efficient catalytic multicomponent reactions (MCRs) is highly sought-
after in chemical synthesis. However, catalytic asymmetric MCRs, particularly involving …

The metal-catalyzed asymmetric addition of phosphorus nucleophiles is one of the most
efficient and reliable approaches for the construction of new carbon–phosphorus bonds. In …

The combination of transition‐metal catalysis and organocatalysis increasingly offers
chemists opportunities to realize diverse unprecedented chemical transformations. By …

Remarkable advances and current state-of-the-art developments in catalytic
hydrophosphination of alkenes and alkynes are reviewed. The challenges in constructing a …

Enantioselective reactions catalyzed by small organic molecules (asymmetric
organocatalysis) have emerged as one of the most elegant cutting-edge strategies of …

By ligand, TEMPO, and base screening, we developed a mild and green one-pot imine
synthesis from alcohols and aminesvia a low-loading palladium-catalyzed tandem aerobic …

Filling the gap for an up-to-date reference that presents the field of organophosphorus
chemistry in a comprehensive and clearly structured way, this one-stop source covers the …

Abstract α‐Aminophosphonates play an important role across several fields, including
organic synthesis and various potential applications. This review paper surveys recent …