Six-membered heterocycles containing one phosphorus and one nitrogen atom, known as
azaphosphinines, have existed in the shadows of their single heteroatom-containing …

This microreview describes progress in the development and coordination chemistry of
donor‐functionalized phosphinines–the phosphorus analogues of pyridines–that has been …

Many parallels have been drawn between the chemistry of low-valent phosphorus and
carbon. This Perspective is intended to highlight some emerging reactivity of …

Abstract The [4+ 2] cycloaddition reaction between 2‐pyrone and Me3Si− C≡ P gives the
corresponding 2‐(trimethylsilyl)‐λ3‐phosphinine in good yields as a rather air and moisture …

We have recently started to investigate the preparation of functionalized phosphinines via
the pyrylium salt route, originally described by Märkl for the synthesis of 2, 4, 6 …

The CoII-catalyzed [2+ 2+ 2] cycloaddition of functionalized diynes and phosphaalkynes
resulting in the formation of an array of structurally interesting phosphinines is reported. A …

This review provides an overview of the most significant strategies developed in recent
years for the preparation of donor-functionalized phosphinines and new developments in …

The manuscript describes the use of a trans-chelated palladium complex derived from 1, 8-
bis-(4-(diphenylphosphino) phenyl) anthracene (1) and p-TolPdI (TMEDA) as a precatalyst …

The reaction of 4, 6-di (tert-butyl)-1, 3, 2-diazaphosphinine (3) with two equivalents of
MeCCPPh2 gave two isomeric products, 2, 6-bis (diphenylphosphino)-3, 5 …

The facile access to 3‐bromo‐2‐pyrone allows the preparation of 6‐bromo‐2‐trimethylsilyl‐
phosphinine by a [4+ 2] cycloaddition with Me3Si‐C≡ P for the first time. The regioselectivity …