Sustainability in catalytic oxidation: an alternative approach or a structural evolution?

F Cavani, JH Teles - ChemSusChem: Chemistry & …, 2009 - Wiley Online Library
Catalytic oxidation provides several examples of the remarkable steps made forward
towards a more sustainable chemical industry: use of alternative reactants, the design of …

VPO catalyst for n-butane oxidation to maleic anhydride: A goal achieved, or a still open challenge?

N Ballarini, F Cavani, C Cortelli, S Ligi, F Pierelli… - Topics in catalysis, 2006 - Springer
This review describes recent findings in the oxidation of n-butane to maleic anhydride. The
process is commercial since the 80's, but yet the yield is far from being optimised. Therefore …

Modeling the selective oxidation of n-butane to maleic anhydride: From active site to industrial reactor

M Müller, M Kutscherauer, S Böcklein, GD Wehinger… - Catalysis Today, 2022 - Elsevier
In this contribution to the Special Issue honoring 100 very successful years of Casale SA, we
review and critically discuss the current status of modeling the most demanding selective …

A Career in Catalysis: Fabrizio Cavani

T Tabanelli, R Mazzoni, N Dimitratos… - ACS …, 2023 - ACS Publications
This Account is to celebrate the 65th birthday of Fabrizio Cavani and his unique and
distinguished career in catalysis, a passionate research work often performed in strong …

On the correlation of structure and catalytic performance of VPO catalysts

S Böcklein, G Mestl, SV Auras, J Wintterlin - Topics in Catalysis, 2017 - Springer
Correlations are reported between structure and performance of current, state-of the art,
industrial maleic anhydride production catalysts. Characterization was done with fully …

Preparation of vanadium phosphate catalyst precursors for the selective oxidation of butane using α, ω-alkanediols

XB Fan, NF Dummer, SH Taylor, JK Bartley… - Catalysis today, 2012 - Elsevier
Vanadium phosphate catalyst precursors were prepared from V2O5 and H3PO4 or VOPO4·
2H2O using α, ω-alkanediols (1, 4-butanediol, 1, 5-pentanediol and 1, 6-hexanediol) as both …

Influence of the oxidation state of vanadium on the reactivity of V/P/O, catalyst for the oxidation of n-pentane to maleic and phthalic anhydrides

G Bignardi, F Cavani, C Cortelli, T De Lucia… - Journal of Molecular …, 2006 - Elsevier
In this paper the role of V5+ and V3+ ions in V/P/O, catalyst for the oxidation of n-pentane to
maleic and phthalic anhydrides, has been investigated. These species have transient …

Partial Oxidation of C2 to C4 Paraffins

F Cavani, F Trifirò - Basic Principles in Applied Catalysis, 2004 - Springer
This review examines the state-of-the-art in the oxidative transformation of C 2-C 4 alkanes
to olefins and to oxygentaed compounds. Chemical, catalytic and technological aspects are …

Partial Oxidation of n-Butane over a Sol-Gel Prepared Vanadium Phosphorous Oxide

JM Salazar, KL Hohn - Catalysts, 2013 - mdpi.com
Vanadium phosphorous oxide (VPO) is traditionally manufactured from solid vanadium
oxides by synthesizing VOHPO4∙ 0.5 H2O (the precursor) followed by in situ activation to …

Study of vanadium containing catalysts for the upgrading of bio-based building blocks

F Puzzo - 2018 - amsdottorato.unibo.it
In the last years, due to the continuous decreasing of the starting material deriving from the
fossil sources and the increasing of the greenhouses emissions, the research has focused …