Cyclometalated [Cp* M (C^ X)](M= Ir, Rh; X= N, C, O, P) complexes
YF Han, GX Jin - Chemical Society Reviews, 2014 - pubs.rsc.org
Half-sandwich Cp* Ir and Cp* Rh metalacycles have been successfully applied in traditional
domains encompassing organic transformations and catalysis in recent years, especially the …
domains encompassing organic transformations and catalysis in recent years, especially the …
Complexes with protic (NH, NH and NH, NR) N-heterocyclic carbene ligands
MC Jahnke, FE Hahn - Coordination Chemistry Reviews, 2015 - Elsevier
The review describes methods for the preparation of complexes bearing protic NHC ligands,
ie NHCs featuring an NH, NH or NH, NR substitution pattern. The protic NHC ligands are …
ie NHCs featuring an NH, NH or NH, NR substitution pattern. The protic NHC ligands are …
Cooperative effects in multimetallic complexes applied in catalysis
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …
catalyze organic transformations to yield the desired products in more efficient ways owing …
Heterometallic complexes, tandem catalysis and catalytic cooperativity
This minireview reports the most recent advances in the use of heterometallic catalysts
based on single-frame N-heterocyclic carbene ligands. The article describes the synthetic …
based on single-frame N-heterocyclic carbene ligands. The article describes the synthetic …
Synthesis, structures, and biological studies of heterobimetallic Au (I)–Ru (II) complexes involving N-heterocyclic carbene-based multidentate ligands
L Boselli, M Carraz, S Mazères, L Paloque… - …, 2015 - ACS Publications
Three heterobimetallic gold (I)–ruthenium (II) complexes containing heteroditopic bipyridine–
N-heterocyclic carbene (NHC) ligands were synthesized and fully characterized by …
N-heterocyclic carbene (NHC) ligands were synthesized and fully characterized by …
Heterobimetallic Complexes Bridged by an Unsymmetrical Bis (NHC) Ligand: Study of Enhanced Catalytic Activity in Tandem Transformations and Understanding of …
The bis (azolium) salt [L1‐H2] Br2 was found to serve as a suitable platform for accessing
the heterobimetallic IrIII‐M (M= PdII/AuI) and PdII‐IrIII complexes. Initially, selective mono …
the heterobimetallic IrIII‐M (M= PdII/AuI) and PdII‐IrIII complexes. Initially, selective mono …
A naphthalene-based heterobimetallic triazolylidene Ir III/Pd II complex: regioselective to regiospecific C–H activation, tandem catalysis and a copper-free …
Heterobimetallic complexes featuring mesoionic carbene (MIC) donor ligands are gaining
enormous popularity in tandem catalysis owing to the combined action of two different metal …
enormous popularity in tandem catalysis owing to the combined action of two different metal …
Donor‐Flexible Nitrogen Ligands for Efficient Iridium‐Catalyzed Water Oxidation Catalysis
A pyridylideneamide ligand with variable donor properties owing to a pronounced
zwitterionic and a neutral diene‐type resonance structure was used as a dynamic ligand at a …
zwitterionic and a neutral diene‐type resonance structure was used as a dynamic ligand at a …
Cyclometalated Mono‐ and Dinuclear IrIII Complexes with “Click”‐Derived Triazoles and Mesoionic Carbenes
Orthometalation at IrIII centers is usually facile, and such orthometalated complexes often
display intriguing electronic and catalytic properties. By using a central phenyl ring as C H …
display intriguing electronic and catalytic properties. By using a central phenyl ring as C H …
IrIII/AuI and RhIII/AuI Heterobimetallic Complexes as Catalysts for the Coupling of Nitrobenzene and Benzylic Alcohol
M Böhmer, F Kampert, TTY Tan… - …, 2018 - ACS Publications
Two simple bisimidazolium salts derived from m-or p-bisimidazolebenzenes have been
used as ligand precursors for the preparation of a series of heterobimetallic RhIII/AuI and …
used as ligand precursors for the preparation of a series of heterobimetallic RhIII/AuI and …