Living alkene polymerization: New methods for the precision synthesis of polyolefins

GJ Domski, JM Rose, GW Coates, AD Bolig… - Progress in polymer …, 2007 - Elsevier
Precise control over product structure is the goal of all chemical synthesis. In the field of
polymer synthesis, the structure of the resultant macromolecule is intimately linked to its …

Tridentate ligands and beyond in group IV metal α-olefin homo-/co-polymerization catalysis

C Redshaw, Y Tang - Chemical Society Reviews, 2012 - pubs.rsc.org
The opening up of new markets, particularly in the Far East, is expected to increase the
industrial demand for more (and new) plastic materials. In turn, this will drive the need for …

Zirconium and titanium diamine bis (phenolate) catalysts for α-olefin polymerization: From atactic oligo (1-hexene) to ultrahigh-molecular-weight isotactic poly (1 …

S Segal, I Goldberg, M Kol - Organometallics, 2005 - ACS Publications
Aiming at higher activities of group IV diamine bis (phenolate) catalysts in olefin
polymerization, ligands containing electron-withdrawing groups have been introduced. The …

Synthesis of Ultrahigh Molecular Weight Ethylene-Based (Co) polymers with Titanium Complexes Bearing Nonsymmetric Amine-bis (phenolate) Ligands

F Li, Y Bai, J He, T Song, W Gao, X Mu, Y Mu - Macromolecules, 2023 - ACS Publications
A series of novel Ti (IV) complexes bearing new type of nonsymmetric amine-bis (phenolate)
tetradentate ligands, Me2NCH2CH2N [2-O-3-R1-5-t BuC6H2][CH2 (2-O-3-R2-5-t BuC6H2)] …

Modern cytotoxic titanium (IV) complexes; Insights on the enigmatic involvement of hydrolysis

EY Tshuva, D Peri - Coordination Chemistry Reviews, 2009 - Elsevier
In this paper, we describe our recent results with three families of Ti (IV) complexes,
elaborating on their cytotoxic activity, hydrolytic behavior, and the potential connection …

Iron complexes for cyclic carbonate and polycarbonate formation: Selectivity control from ligand design and metal-center geometry

KA Andrea, ED Butler, TR Brown, TS Anderson… - Inorganic …, 2019 - ACS Publications
A family of 17 iron (III) aminobis (phenolate) complexes possessing different phenolate
substituents, coordination geometries, and donor arrangements were used as catalysts for …

C3 chirality in polymerization catalysis: a highly active dicationic scandium (III) catalyst for the isoselective polymerization of 1-hexene

BD Ward, S Bellemin-Laponnaz… - Angewandte Chemie …, 2005 - orca.cardiff.ac.uk
A tactical approach: C3-chiral ancillary ligands such as tris (oxazolinyl) ethane allow
stereocontrol in olefin polymerization (see scheme). An alkyl ScIII catalyst polymerizes 1 …

Structural properties and applications of multidentate [O, N, O, X′] aminobisphenolate metal complexes

O Wichmann, R Sillanpää, A Lehtonen - Coordination Chemistry Reviews, 2012 - Elsevier
Aminobisphenols with side-arm donors are versatile tetradentate ligands that effectively
coordinate to the metal ions in a tripodal fashion. Most of the metal ions form electrically …

Phosphorus and olefin substituent effects on the insertion chemistry of nickel (II) hydride complexes containing amido diphosphine ligands

LC Liang, PS Chien, PY Lee - Organometallics, 2008 - ACS Publications
A series of nickel (II) hydride complexes supported by amido diphosphine ligands, including
symmetrical [N (o-C6H4PR2) 2]−([R-PNP]−; R= Ph, i Pr, Cy) and unsymmetrical [N (o …

Zirconium and Titanium Complexes Supported by Tridentate LX2 Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for …

T Agapie, LM Henling, AG DiPasquale… - …, 2008 - ACS Publications
Zirconium and titanium complexes with tridentate bis (phenolate)− donor (donor= pyridine,
furan and thiophene) ligands have been prepared and investigated for applications in …