Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Recent advances in minisci‐type reactions

RSJ Proctor, RJ Phipps - Angewandte Chemie International …, 2019 - Wiley Online Library
Reactions that involve the addition of carbon‐centered radicals to basic heteroarenes,
followed by formal hydrogen atom loss, have become widely known as Minisci‐type …

Organoelectrophotocatalytic Generation of Acyl Radicals from Formamides and Aldehydes: Access to Acylated 3-CF3-2-Oxindoles

H He, Q Wan, ZW Hou, Q Zhou, L Wang - Organic Letters, 2023 - ACS Publications
Organoelectrophotocatalytic generation of acyl radicals from formamides and aldehydes to
synthesize acylated 3-CF3-2-oxindoles has been developed. This protocol features a …

[图书][B] Visible light photocatalysis in organic chemistry

CRJ Stephenson, TP Yoon, DWC MacMillan - 2018 - books.google.com
Filling the need for a ready reference that reflects the vast developments in this field, this
book presents everything from fundamentals, applications, various reaction types, and …

Photochemical nickel-catalyzed C–H arylation: synthetic scope and mechanistic investigations

DR Heitz, JC Tellis, GA Molander - Journal of the American …, 2016 - ACS Publications
An iridium photocatalyst and visible light facilitate a room temperature, nickel-catalyzed
coupling of (hetero) aryl bromides with activated α-heterosubstituted or benzylic C (sp3)–H …

Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

L Marzo, SK Pagire, O Reiser, B König - Angewandte Chemie, 2018 - Wiley Online Library
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …

Hydrogen atom transfer-driven enantioselective minisci reaction of amides

RSJ Proctor, P Chuentragool, AC Colgan… - Journal of the …, 2021 - ACS Publications
Minisci-type reactions constitute one of the most powerful methods for building up
complexity around basic heteroarenes. The most desirable variants involve formal oxidative …

Photogenerated acyl/alkoxycarbonyl/carbamoyl radicals for sustainable synthesis

C Raviola, S Protti, D Ravelli, M Fagnoni - Green Chemistry, 2019 - pubs.rsc.org
Acylation reactions are of crucial importance in synthesis since they provide access to
ketones or related derivatives. The well known acylations of aromatics (the Friedel–Crafts …

Ritter-type amination of C(sp3)-H bonds enabled by electrochemistry with SO42−

L Zhang, Y Fu, Y Shen, C Liu, M Sun, R Cheng… - Nature …, 2022 - nature.com
By merging electricity with sulfate, the Ritter-type amination of C (sp3)-H bonds is developed
in an undivided cell under room temperature. This method features broad substrate …

Photo-induced cross-dehydrogenative alkylation of heteroarenes with alkanes under aerobic conditions

J Xu, H Cai, J Shen, C Shen, J Wu… - The Journal of Organic …, 2021 - ACS Publications
We report a Minisci-type cross-dehydrogenative alkylation in an aerobic atmosphere using
abundant and inexpensive cerium chloride as a photocatalyst and air as an oxidant. This …