The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

Enantiomerically enriched five‐and six‐membered benzo oxygen heterocycles are
privileged architectures in functional organic molecules. Over the last several years, many …

We have developed a photoinduced copper‐catalyzed alkylation of terminal alkynes with
primary, secondary, or tertiary alkyl iodides as electrophiles. The reaction has a broad …

A highly enantioselective copper‐catalyzed alkynylation of quinolinium salts is reported. The
reaction employs StackPhos, a newly developed imidazole‐based chiral biaryl P, N ligand …

A direct enantioselective synthesis of substituted oxygen heterocycles from lactol acetates
and enolsilanes has been realized using a highly reactive and confined …

Although catalytic enantioselective alkyne addition is an established method for the
synthesis of chiral propargylic alcohols and amines, addition to nitrones presents unique …

The first catalytic enantioselective alkynylation of chromones is reported. In this process,
chromones are silylated to form silyloxybenzopyrylium ions that lead to silyl enol ethers after …

An enantioselective catalytic inverse-electron-demand Diels–Alder reaction of
salicylaldehyde acetal-derived oxocarbenium ions and vinyl ethers to generate 2, 4 …

Catalytic asymmetric syntheses of enantioenriched propargyl alcohols and amines have
been a central topic in organic synthesis. Toward this, a great deal of research has been put …

Abstract An enantioselective, copper (I)‐catalyzed addition of terminal alkynes to
isochroman ketals to set diaryl, tetrasubstituted stereocenters has been developed. The …