3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Cross-coupling of heteroatomic electrophiles

KM Korch, DA Watson - Chemical reviews, 2019 - ACS Publications
At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

Copper-catalyzed stereospecific transformations of alkylboronic esters

N Xu, H Liang, JP Morken - Journal of the American Chemical …, 2022 - ACS Publications
Copper-catalyzed stereospecific cross-couplings of boronic esters are reported. Boron “ate”
complexes derived from pinacol boronic esters and tert-butyl lithium undergo stereospecific …

Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update

X Zhu, S Chiba - Chemical Society Reviews, 2016 - pubs.rsc.org
Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update - Chemical
Society Reviews (RSC Publishing) DOI:10.1039/C5CS00882D Royal Society of Chemistry …

Recent advances in metal free-and late transition metal-catalysed hydroamination of unactivated alkenes

E Bernoud, C Lepori, M Mellah, E Schulz… - Catalysis Science & …, 2015 - pubs.rsc.org
This Perspective article outlines some of the recent advancements completed in the
development of (chiral) metal-free and late-transition metal catalysts for the inter-and …

Cobalt-catalyzed electrophilic aminations with anthranils: an expedient route to condensed quinolines

J Li, E Tan, N Keller, YH Chen… - Journal of the …, 2018 - ACS Publications
The reaction of various organozinc pivalates with anthranils provides anilines derivatives,
which cyclize under acidic conditions providing condensed quinolines. Using alkenylzinc …

Directed, nickel-catalyzed umpolung 1, 2-carboamination of alkenyl carbonyl compounds

VA van der Puyl, J Derosa, KM Engle - ACS Catalysis, 2018 - ACS Publications
We report a regioselective, nickel-catalyzed syn-1, 2-carboamination of nonconjugated
alkenyl carbonyl compounds with O-benzoyl hydroxylamine (N–O) electrophiles and …

Copper-catalyzed carboxylation reactions using carbon dioxide

S Wang, G Du, C Xi - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
Carbon dioxide (CO2), as a waste of manufacture, is a cheap and abundant C1 source.
Utilization of CO2 for synthesis of carboxylic acids has been developed. Transition-metal …

Transition‐Metal‐Catalyzed Electrophilic Amination: Application of O‐Benzoylhydroxylamines in the Construction of the C−N Bond

X Dong, Q Liu, Y Dong, H Liu - Chemistry–A European Journal, 2017 - Wiley Online Library
Transition‐metal‐catalyzed electrophilic amination has been developed into a powerful tool
for C− N bond construction. So far, O‐benzoylhydroxylamines are the most widely used …

Design of modified amine transfer reagents allows the synthesis of α-chiral secondary amines via CuH-catalyzed hydroamination

D Niu, SL Buchwald - Journal of the American Chemical Society, 2015 - ACS Publications
The CuH-catalyzed hydroamination of alkenes and alkynes using a silane and an amine
transfer reagent represents a simple strategy to access chiral amine products. We have …