Electrochemistry at one nanoparticle

MV Mirkin, T Sun, Y Yu, M Zhou - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Electrochemistry at metal nanoparticles (NPs) is of significant current interest
because of its applications in catalysis, energy conversion and storage, and sensors. The …

Observation of single-protein and DNA macromolecule collisions on ultramicroelectrodes

JE Dick, C Renault, AJ Bard - Journal of the American Chemical …, 2015 - ACS Publications
Single-molecule detection is the ultimate sensitivity in analytical chemistry and has been
largely unavailable in electrochemical analysis. Here, we demonstrate the feasibility of …

Collision dynamics during the electrooxidation of individual silver nanoparticles

DA Robinson, Y Liu, MA Edwards, NJ Vitti… - Journal of the …, 2017 - ACS Publications
Recent high-bandwidth recordings of the oxidation and dissolution of 35 nm radius Ag
nanoparticles at a Au microelectrode show that these nanoparticles undergo multiple …

On Practical Aspects of Single-Entity Electrochemical Measurements with Hot Microelectrodes

A Boika - Analytical Chemistry, 2023 - ACS Publications
When a 10s–100s MHz frequency alternating current (ac) waveform is applied to a disk
ultramicroelectrode (UME) in an electrochemical cell, one achieves what is known as a hot …

Toward the detection and identification of single bacteria by electrochemical collision technique

G Gao, D Wang, R Brocenschi, J Zhi… - Analytical …, 2018 - ACS Publications
Fast and cost-efficient detection and identification of bacteria in food and water samples and
biological fluids is an important challenge in bioanalytical chemistry. It was shown recently …

Detection of bacterial rhamnolipid toxin by redox liposome single impact electrochemistry

J Luy, D Ameline, C Thobie‐Gautier… - Angewandte …, 2022 - Wiley Online Library
The detection of Rhamnolipid virulence factor produced by Pseudomonas aeruginosa
involved in nosocomial infections is reported by using the redox liposome single impact …

Influence of electroosmotic flow on stochastic collisions at ultramicroelectrodes

SN Thorgaard, S Jenkins, AR Tarach - Analytical Chemistry, 2020 - ACS Publications
The collision events of single Lactococcus lactis bacteria at Pt disk ultramicroelectrodes
(UMEs) were characterized using electrochemistry with correlated microscopy. A finite …

Collisions of Ir oxide nanoparticles with carbon nanopipettes: experiments with one nanoparticle

M Zhou, Y Yu, K Hu, HL Xin, MV Mirkin - Analytical chemistry, 2017 - ACS Publications
Investigating the collisions of individual metal nanoparticles (NPs) with electrodes can
provide new insights into their electrocatalytic behavior, mass transport, and interactions …

Recognizing Single Collisions of PtCl62– at Femtomolar Concentrations on Ultramicroelectrodes by Nucleating Electrocatalytic Clusters

JE Dick, AJ Bard - Journal of the American Chemical Society, 2015 - ACS Publications
We report the electrodeposition of electrocatalytic clusters of platinum from femtomolar
platinate solutions. An inert carbon fiber ultramicroelectrode (UME) was held at a potential …

Blocking electrochemical collisions of single E. coli and B. subtilis bacteria at ultramicroelectrodes elucidated using simultaneous fluorescence microscopy

AT Ronspees, SN Thorgaard - Electrochimica Acta, 2018 - Elsevier
The adsorption events and movements of individual E. coli and B. subtilis bacteria were
detected in real time using ultramicroelectrodes (UMEs). Electrochemical detection of single …