For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

The photo-/electrocatalytic functionalization of quinoxalin-2 (1H)-ones has emerged as a
promising and powerful approach for post-synthetic modification of quinoxalin-2 (1H)-ones …

Oximes are valuable synthetic building blocks with reactivity modes that enable their use in
diverse methodologies, from cycloadditions to bioconjugation. Their reactivity towards …

Recent years have witnessed a renaissance of radical cross‐coupling of cycloketone
oximes which served as active cyanoalkyl radical via ring fragmentation in various …

An SN 2-based photochemical strategy using dithiocarbamate anion as catalyst was
developed for the activation of benzyl halides, which are extremely challenging to be …

We report, for the first time, a visible-light-promoted direct C3 alkylation of quinoxalin-2 (1H)-
ones and coumarins using readily accessible unactivated alkyl iodides as alkylation …

Reported herein is a photoredox-catalyzed amination of o-hydroxyarylenaminones with tert-
butyl ((perfluoropyridin-4-yl) oxy) carbamate, a versatile amidyl-radical precursor developed …

Visible‐light‐mediated chemical reactions have become highly popular in the last ten years.
This review covers the recent developments in visible‐light photofunctionalization of …

Reported herein is the design and synthesis of new O-perhalopyridin-4-yl hydroxylamines
as shelf-stable and versatile amidyl-radical precursors. The novel amination reagents can …