Photochromism of diarylethene molecules and crystals: memories, switches, and actuators

M Irie, T Fukaminato, K Matsuda, S Kobatake - Chemical Reviews, 2014 - ACS Publications
Photochromism is defined as a reversible transformation of a chemical species between two
isomers having different absorption spectra induced in one or both directions by …

Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Supramolecular complex of photochromic diarylethene and cucurbit [7] uril: fluorescent photoswitching system for biolabeling and imaging

D Kim, A Aktalay, N Jensen, K Uno… - Journal of the …, 2022 - ACS Publications
Photoswitchable fluorophores─ proteins and synthetic dyes─ whose emission is reversibly
switched on and off upon illumination, are powerful probes for bioimaging, protein tracking …

Photo-actuators via epitaxial growth of microcrystal arrays in polymer membranes

W Xu, DM Sanchez, U Raucci, H Zhou, X Dong, M Hu… - Nature Materials, 2023 - nature.com
Photomechanical crystals composed of three-dimensionally ordered and densely packed
photochromes hold promise for high-performance photochemical actuators. However, bulk …

Femtosecond crystallography with ultrabright electrons and x-rays: Capturing chemistry in action

RJD Miller - Science, 2014 - science.org
With the recent advances in ultrabright electron and x-ray sources, it is now possible to
extend crystallography to the femtosecond time domain to literally light up atomic motions …

Photochemical mechanisms of fluorophores employed in single‐molecule localization microscopy

K Kikuchi, LD Adair, J Lin, EJ New… - Angewandte Chemie, 2023 - Wiley Online Library
Decoding cellular processes requires visualization of the spatial distribution and dynamic
interactions of biomolecules. It is therefore not surprising that innovations in imaging …

Capturing chemistry in action with electrons: realization of atomically resolved reaction dynamics

AA Ischenko, PM Weber, RJD Miller - Chemical reviews, 2017 - ACS Publications
One of the grand challenges in chemistry has been to directly observe atomic motions
during chemical processes. The depiction of the nuclear configurations in space-time to …

Reversibly photoswitchable fluorescent diarylethenes resistant against photobleaching in aqueous solutions

K Uno, ML Bossi, M Irie, VN Belov… - Journal of the American …, 2019 - ACS Publications
Low photostability in aqueous solutions is the main drawback of synthetic photochromic
dyes, which limits their switching performance and utility in biology, medicine, and life …

Shape permanence in diarylethene‐functionalized liquid‐crystal elastomers facilitated by thiol‐anhydride dynamic chemistry

TS Hebner, M Podgórski, S Mavila… - Angewandte Chemie …, 2022 - Wiley Online Library
Diarylethene‐functionalized liquid‐crystalline elastomers (DAE‐LCEs) containing thiol‐
anhydride bonds were prepared and shown to undergo reversible, reprogrammable …

Switching diarylethenes reliably in both directions with visible light

S Fredrich, R Göstl, M Herder… - Angewandte Chemie …, 2016 - Wiley Online Library
A diarylethene photoswitch was covalently connected to two small triplet sensitizer moieties
in a conjugated and nonconjugated fashion and the photochromic performance of the …