Photochemical reactions offer unparalleled opportunities to access elusive chemical
pathways and develop innovative strategies for constructing complex molecules. Within …

An efficient base, additive and metal-free synthetic methods for α-ketothioamide and α-
ketoamide derivatives from readily available sulfoxonium ylides have been described …

A novel straightforward and catalyst-free approach for synthesizing quinoxaline derivatives
from sulfoxonium ylides and o-phenylenediamines mediated by elemental sulfur has been …

A novel visible-light-promoted coupling of diazoketones with sulfoxonium ylides, employing
a violet light-emitting diode, is described under both batch and continuous flow conditions …

Herein, a method to access 3-trifluoromethyl-1, 4-benzoxazines from CF3-imidoyl
sulfoxonium ylides and 2-bromophenols has been demonstrated. This synthetic protocol …

Disclosed here is a catalytic asymmetric azidation reaction for the efficient synthesis of α-
azido ketones bearing a labile tertiary stereocenter. With a superb chiral squaramide …

Efficient, versatile, and metal-free strategies for synthesizing α-thiocyanoketones and
thiazoles from β-ketosulfoxonium ylides and ammonium thiocyanate have been described …

Simple, versatile, and catalyst-free synthetic methods for β-keto dithiocarbamates,
thiazolidine-2-thiones, and thiazole-2-thiones via the multicomponent reaction of CS2 …

Abstract A novel I2‐DMSO‐mediated cascade cyclization approach for synthesizing 2‐
hydroxy‐pyrrol‐3 (2H)‐one scaffold from readily accessible β‐ketosulfoxonium ylides and β …

An iron-catalysed radical azidation of iododifluoroketones with TMSN3 was developed
under mild reaction conditions, providing a concise synthesis of α-difluoroalkylazides. The …