Dinitrogen binding at a trititanium chloride complex and its conversion to ammonia under ambient conditions
E Del Horno, J Jover, M Mena… - Angewandte …, 2022 - Wiley Online Library
Abstract Reaction of [TiCp* Cl3](Cp*= η5‐C5Me5) with one equivalent of magnesium in
tetrahydrofuran at room temperature affords the paramagnetic trinuclear complex [{TiCp*(μ …
tetrahydrofuran at room temperature affords the paramagnetic trinuclear complex [{TiCp*(μ …
Half-Sandwich Zirconium and Hafnium Amidoborane Complexes: Precursors of Hydride Derivatives
M Greño, A Pérez-Redondo, J Torrijos… - Inorganic …, 2024 - ACS Publications
Half-sandwich zirconium (IV) and hafnium (IV) complexes with amidoborane and hydride
ligands have been isolated in the stoichiometric reactions of mono …
ligands have been isolated in the stoichiometric reactions of mono …
Low‐Valent Titanium Species Stabilized with Aluminum/Boron Hydride Fragments
E Del Horno, J Jover, M Mena… - … A European Journal, 2022 - Wiley Online Library
Low‐valent titanium species were prepared by reaction of [TiCp* X3](Cp*= η5‐C5Me5; X=
Cl, Br, Me) with LiEH4 (E= Al, B) or BH3 (thf), and their structures elucidated by experimental …
Cl, Br, Me) with LiEH4 (E= Al, B) or BH3 (thf), and their structures elucidated by experimental …
Ammonia‐Borane Derived BN Fragments Trapped on Bi‐and Trimetallic Titanium (III) Systems
E Del Horno, J Jover, M Mena… - … A European Journal, 2019 - Wiley Online Library
Titanium (III) complexes containing unprecedented (NH2BH2NHBH3) 2− and {N (BH3) 3} 3−
ligands have been isolated, and their structures elucidated by a combination of experimental …
ligands have been isolated, and their structures elucidated by a combination of experimental …
Unexpected Selective Methyl Group Abstractions from SiMe3 Moieties of CH2SiMe3 Ligands To Give New Cationic Titanium Complexes
M Fischer, D Barbul, M Schmidtmann… - … –A European Journal, 2019 - Wiley Online Library
The synthesis of the alkylated pentafulvene titanium complex Cp* Ti (CH2SiMe3)(π‐η5: σ‐
η1‐C5H4= CR2)(CR2= adamantylidene) is described. The coordination mode of the …
η1‐C5H4= CR2)(CR2= adamantylidene) is described. The coordination mode of the …
X-Ray Crystal Structures of Two Monopentamethylcyclopentadienylhafnium (IV) Complexes
M Mena, A Pérez-Redondo, V Varela-Izquierdo… - Crystallography …, 2021 - Springer
The crystal structures of two monopentamethylcyclopentadienylhafnium (IV) derivatives
have been determined by X-ray diffraction analysis. The [Hf (η5-C5 Me 5) Cl3] complex (I) …
have been determined by X-ray diffraction analysis. The [Hf (η5-C5 Me 5) Cl3] complex (I) …
[引用][C] Cyclopentadienyl and Phospholyl Complexes of the Group 4 Metals
AFR Kilpatrick, FM Chadwick - 2022 - Elsevier
[引用][C] Alkylidene Complexes of the Group 4 Transition Metals
DJ Mindiola, JR Aguilar-Calderón, P Zatsepin - 2022 - Elsevier