Metal and ligand effects of photoactive transition metal carbonyls in the iodine degenerative transfer controlled radical polymerization and block copolymerization of …

CP Simpson, OI Adebolu, JS Kim, V Vasu… - …, 2015 - ACS Publications
The metal and ligand effect of a series of transition metal carbonyls in conjunction with alkyl
and perfluoroalkyl halides was investigated in the initiation and control of the visible light …

Silica nanospheres supported diazafluorene iron complex: an efficient and versatile nanocatalyst for the synthesis of propargylamines from terminal alkynes …

RK Sharma, S Sharma, G Gaba - RSC Advances, 2014 - pubs.rsc.org
We present the synthesis of an efficient heterogeneous silica nanosphere supported iron
catalyst (SiO2@ APTES@ DAFO-Fe) and its catalytic application in a one pot three …

Activation of aryl halides by nickel (I) pincer complexes: reaction pathways of stoichiometric and catalytic dehalogenations

CA Rettenmeier, J Wenz, H Wadepohl… - Inorganic …, 2016 - ACS Publications
Homolytic C–X bond cleavage of organohalides by the T-shaped nickel (I) complexes
[LigNiI] 1 bearing the iso-PyrrMeBox ligand had been found previously to be the crucial …

A unified set of experimental organometallic data used to evaluate modern theoretical methods

RK Raju, AA Bengali, EN Brothers - Dalton Transactions, 2016 - pubs.rsc.org
We applied a test set of ligand dissociation enthalpies derived entirely from a unified
experimental approach to evaluate the efficacy of various methods for modeling …

A Caged Neutral 17-Valence-Electron Iron(I) Radical [Fe(CO)2(Cl)(P((CH2)10)3P)]: Synthetic, Structural, Spectroscopic, Redox, and Computational Studies

SR Zarcone, Z Zhang, S Handunneththige… - Inorganic …, 2024 - ACS Publications
UV irradiation of yellow CH2Cl2 solutions of trans-Fe (CO) 3 (P ((CH2) 10) 3 P)(2a) and
PMe3 (10 equiv) gives, in addition to the previously reported dibridgehead diphosphine P …

Nickel (II)-2-amino-4-alkoxy-1, 3, 5-triazapentadienate complexes as catalysts for Heck and Henry reactions

APC Ribeiro, YY Karabach, LM Martins… - RSC …, 2016 - pubs.rsc.org
Nickel (II)-triazapentadienate complexes,[Ni (tap) 2], are synthesized and found to act as
catalysts in the Heck reaction of deactivated aryl halides. The use of room-temperature ionic …

Thermal dehydrogenation of dimethylamine borane catalyzed by a bifunctional rhenium complex

V Yempally, S Moncho, Y Wang, SJ Kyran… - …, 2019 - ACS Publications
The reaction of a bidentate pyrrole based rhenium tetracarbonyl complex with
dimethylamine borane at room temperature results in rapid dehydrogenation. Hydrogen …

Synthesis and catalytic activity of supported acenaphthoimidazolylidene N-heterocyclic carbene ruthenium complex for ring closing metathesis (RCM) and ring …

AR Hlil, S Moncho, R Tuba, K Elsaid, G Szarka… - Journal of …, 2016 - Elsevier
Ruthenium catalyzed ring closing metathesis (RCM) and ring opening metathesis
polymerization (ROMP) reactions using a supported bis (arylimino) acenaphthene N …

Stereochemistry of oxidative addition reactions of cycloneophyl complexes of Platinum (II): A methylene insertion reaction from dichloromethane

MA Fard, A Behnia, RJ Puddephatt - Journal of Organometallic Chemistry, 2019 - Elsevier
Unusual features are observed in studies of oxidative addition to cycloneophylplatinum (II)
complexes [Pt (CH 2 CMe 2 C 6 H 4)(NN)], 2, NN= 3, 4, 7, 8-tetramethyl-1, 10 …

New C-scorpionate nickel (II) catalyst for Heck C–C coupling under unconventional conditions

IAS Matias, APC Ribeiro, LM Martins - Journal of Organometallic Chemistry, 2019 - Elsevier
The new C-scorpionate Ni (II) complex [NiCl {κ 3-HC (pz) 3}] Cl (pz= pyrazol-1-yl) is the first
nickel homoscorpionate tris (pyrazol-1-yl) methane type complex to be applied as catalyst …