Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Bistable Spin‐Crossover Nanoparticles for Molecular Electronics

R Torres‐Cavanillas, M Gavara‐Edo… - Advanced …, 2024 - Wiley Online Library
The field of spin‐crossover complexes is rapidly evolving from the study of the spin transition
phenomenon to its exploitation in molecular electronics. Such spin transition is gradual in a …

Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

L Kipgen, M Bernien, F Tuczek, W Kuch - Advanced Materials, 2021 - Wiley Online Library
Molecular spintronics seeks to use single or few molecules as functional building blocks for
spintronic applications, directly relying on molecular properties or properties of interfaces …

Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

Spin-state-dependent electrical conductivity in single-walled carbon nanotubes encapsulating spin-crossover molecules

J Villalva, A Develioglu… - Nature …, 2021 - nature.com
Spin crossover (SCO) molecules are promising nanoscale magnetic switches due to their
ability to modify their spin state under several stimuli. However, SCO systems face several …

Spin-crossover in iron (II)-Schiff base complexes

KS Kumar, Y Bayeh, T Gebretsadik, F Elemo… - Dalton …, 2019 - pubs.rsc.org
The spin-crossover (SCO) phenomenon is one of the most prominent examples of bi-stability
in molecular chemistry, and the SCO complexes are proposed for nanotechnological …

The influence of the substrate on the functionality of spin crossover molecular materials

S Yazdani, J Phillips, TK Ekanayaka, R Cheng… - Molecules, 2023 - mdpi.com
Spin crossover complexes are a route toward designing molecular devices with a facile
readout due to the change in conductance that accompanies the change in spin state …

Spin-crossover complexes in direct contact with surfaces

M Gruber, R Berndt - Magnetochemistry, 2020 - mdpi.com
The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted
considerable interest in recent years. The deposition of the complexes on surfaces allows …

Understanding of cooperative effects in molecule-based spin transition materials

Y Fang, YS Meng, H Oshio, T Liu - Coordination Chemistry Reviews, 2024 - Elsevier
Spin transition (ST) materials, exhibiting spin state conversions by external stimuli, have
been studied for over a half-century and have been continuing research interests owing to …

Room temperature conductance switching in a molecular iron (iii) spin crossover junction

SK Karuppannan, A Martín-Rodríguez, E Ruiz… - Chemical …, 2021 - pubs.rsc.org
Herein, we report the first room temperature switchable Fe (III) molecular spin crossover
(SCO) tunnel junction. The junction is constructed from [FeIII (qsal-I) 2] NTf2 (qsal-I= 4-iodo-2 …