When systems that can undergo phase separation between two coexisting phases in the bulk are confined in thin film geometry between parallel walls, the phase behavior can be …
The complexation of mixtures of cationic and anionic polymers to produce complex- coacervate phases is a subject of fundamental importance to colloid and polymer science as …
JT Siebert, F Dittrich, F Schmid, K Binder, T Speck… - Physical Review E, 2018 - APS
We study active Brownian particles as a paradigm for a genuine nonequilibrium phase transition requiring steady driving. Access to the critical point in computer simulations is …
The thermodynamic behavior of a fluid near a vapor-liquid and, hence, asymmetric critical point is discussed within a general “complete” scaling theory incorporating pressure mixing …
We consider the problem of charge correlations in self-coacervate phases of polyampholytes and disordered proteins with different monomer sequences. An analytical …
We investigate phase transitions of two-dimensional Ising models with power-law interactions, using an efficient Monte Carlo algorithm. For slow decay, the transition is of the …
M Wagner, O Stanga, W Schröer - Physical Chemistry Chemical …, 2003 - pubs.rsc.org
A systematic study of liquid–liquid phase transitions in mixtures of room temperature ionic liquids (RTIL) with nonionic solvents of different dielectric constant is presented. We report …
The net charge of solvated entities, ranging from polyelectrolytes and biomolecules to charged nanoparticles and membranes, depends on the local dissociation equilibrium of …
Recent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are reviewed. Selected experimental, simulation, and theoretical results for electrochemical …