1. INTRODUCTION Phthalocyanine metal complexes 1, 2 (MPc's) are structurally related to
porphyrin complexes (Figure 1), which are widely used by nature in the active sites of …

Conspectus The ultimate objective of bioinspired catalysis is the development of efficient
and clean chemical processes. Cytochrome P450 and soluble methane monooxygenase …

High-valent oxo–metal complexes are involved in key biochemical processes of selective
oxidation and removal of xenobiotics. The catalytic properties of cytochrome P-450 and …

Carbon–fluorine bonds are the strongest single bonds in organic chemistry, making
activation and cleavage usually associated with organometallic and reductive approaches …

The photophysical properties of a newly synthesized unsymmetrically substituted zinc
phthalocyanine derivative (1) bearing in its peripheral positions six n-hexylsulfanyl …

Iron (IV)–oxo species have been identified as the active intermediates in key enzymatic
processes, and their catalytic properties are strongly affected by the equatorial and axial …

The enormous challenge of moving our societies to a more sustainable future offers several
exciting opportunities for computational chemists. The first principles approach to “catalysis …

Oxidation is one of the fundamental transformations in organic synthesis. The selective
oxidation of inert substrates is interesting and important. In this review, the transition metal …

We show that the ability of the ligand to reorganize the electric double layer (EDL) often
dominates the electrocatalysis contrary to their inductive effect in the spectrochemical series …

The electronic structure of three single-atom bridged diiron octapropylporphyrazine
complexes (FePzPr8) 2X having Fe (III)–O–Fe (III), Fe (III)–N–Fe (IV) and Fe (IV)–C–Fe (IV) …