Main group chemistry at the interface with molecular magnetism
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …
heart of advances in molecular magnetism. Smart ligand design is essential for …
Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets
The discovery that some bis-(phthalocyaninato) lanthanide complexes are molecular
magnets triggered interest in lanthanide ion complexes. Theoretical and experimental …
magnets triggered interest in lanthanide ion complexes. Theoretical and experimental …
Exploring the Influence of Diamagnetic Ions on the Mechanism of Magnetization Relaxation in {CoIII2LnIII2} (Ln = Dy, Tb, Ho) “Butterfly” Complexes
KR Vignesh, SK Langley, KS Murray… - Inorganic …, 2017 - ACS Publications
The synthesis and magnetic and theoretical studies of three isostructural heterometallic
[CoIII2LnIII2 (μ3-OH) 2 (o-tol) 4 (mdea) 2 (NO3) 2](Ln= Dy (1), Tb (2), Ho (3))“butterfly” …
[CoIII2LnIII2 (μ3-OH) 2 (o-tol) 4 (mdea) 2 (NO3) 2](Ln= Dy (1), Tb (2), Ho (3))“butterfly” …
Slow Magnetic Relaxation and Single‐Molecule Toroidal Behaviour in a Family of Heptanuclear {CrIIILnIII6} (Ln=Tb, Ho, Er) Complexes
KR Vignesh, SK Langley, A Swain… - Angewandte …, 2018 - Wiley Online Library
The synthesis, magnetic properties, and theoretical studies of three heterometallic
{CrIIILnIII6}(Ln= Tb, Ho, Er) complexes, each containing a metal topology consisting of two …
{CrIIILnIII6}(Ln= Tb, Ho, Er) complexes, each containing a metal topology consisting of two …
Low coordinated mononuclear erbium (iii) single-molecule magnets with C 3v symmetry: a method for altering single-molecule magnet properties by incorporating …
H Zhang, R Nakanishi, K Katoh, BK Breedlove… - Dalton …, 2018 - pubs.rsc.org
Structures and magnetic characteristics of two three-coordinate erbium (III) compounds with
C3v geometry, tris (2, 6-di-tert-butyl-p-cresolate) erbium, Er (dbpc) 3 (1) and tris (bis …
C3v geometry, tris (2, 6-di-tert-butyl-p-cresolate) erbium, Er (dbpc) 3 (1) and tris (bis …
New examples of triangular terbium (III) and holmium (III) and hexagonal dysprosium (III) single molecule toroics
The structural, magnetic and theoretical aspects are described for three triangular
lanthanide complexes,[TbIII3 (OH)(teaH2) 3 (paa) 3] Cl2 (1),[DyIII3 (OH)(teaH2) 3 (paa) 3] …
lanthanide complexes,[TbIII3 (OH)(teaH2) 3 (paa) 3] Cl2 (1),[DyIII3 (OH)(teaH2) 3 (paa) 3] …
Is a strong axial crystal-field the only essential condition for a large magnetic anisotropy barrier? The case of non-Kramers Ho (III) versus Tb (III)
A monometallic non-Kramers Ho (III) complex with a strong uniaxial ligand field displays a
record high energy barrier of 355 K with hysteresis opening up to 4 K at a sweep rate of …
record high energy barrier of 355 K with hysteresis opening up to 4 K at a sweep rate of …
High-pressure synthesis of dysprosium carbides
FI Akbar, A Aslandukova, A Aslandukov, Y Yin… - Frontiers in …, 2023 - frontiersin.org
Chemical reactions between dysprosium and carbon were studied in laser-heated diamond
anvil cells at pressures of 19, 55, and 58 GPa and temperatures of∼ 2500 K. In situ single …
anvil cells at pressures of 19, 55, and 58 GPa and temperatures of∼ 2500 K. In situ single …
Influence of the ligand field on the slow relaxation of magnetization of unsymmetrical monomeric lanthanide complexes: synthesis and theoretical studies
A series of monomeric lanthanide Schiff base complexes with the molecular formulas [Ce
(HL) 3 (NO3) 3](1) and [Ln (HL) 2 (NO3) 3], where LnIII= Tb (2), Ho (3), Er (4), and Lu (5) …
(HL) 3 (NO3) 3](1) and [Ln (HL) 2 (NO3) 3], where LnIII= Tb (2), Ho (3), Er (4), and Lu (5) …
New field-induced single ion magnets based on prolate Er (iii) and Yb (iii) ions: tuning the energy barrier U eff by the choice of counterions within an N 3-tridentate …
Lanthanides have relatively recently been recognized as ideal candidates for the
construction of advanced magnetic materials that would allow for their future applications in …
construction of advanced magnetic materials that would allow for their future applications in …