Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023 - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Luminescent first-row transition metal complexes

C Wegeberg, OS Wenger - Jacs Au, 2021 - ACS Publications
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …

Exploiting the Marcus inverted region for first-row transition metal–based photoredox catalysis

AY Chan, A Ghosh, JT Yarranton, J Twilton, J Jin… - Science, 2023 - science.org
Second-and third-row transition metal complexes are widely employed in photocatalysis,
whereas earth-abundant first-row transition metals have found only limited use because of …

Photoredox-active Cr (0) luminophores featuring photophysical properties competitive with Ru (II) and Os (II) complexes

N Sinha, C Wegeberg, D Häussinger, A Prescimone… - Nature Chemistry, 2023 - nature.com
Coordination complexes of precious metals with the d6 valence electron configuration such
as Ru (II), Os (II) and Ir (III) are used for lighting applications, solar energy conversion and …

Single‐Component 0D Metal–Organic Halides with Color‐Variable Long‐Afterglow toward Multi‐Level Information Security and White‐Light LED

T Chen, YJ Ma, D Yan - Advanced Functional Materials, 2023 - Wiley Online Library
The optical anti‐counterfeiting science and technology are currently restricted by the limited
information loading capacity, and thus development of multi‐level and high‐security systems …

Dynamics of excitons in conjugated molecules and organic semiconductor systems

OP Dimitriev - Chemical Reviews, 2022 - ACS Publications
The exciton, an excited electron–hole pair bound by Coulomb attraction, plays a key role in
photophysics of organic molecules and drives practically important phenomena such as …

Manganese(i) complexes with metal-to-ligand charge transfer luminescence and photoreactivity

P Herr, C Kerzig, CB Larsen, D Häussinger… - Nature Chemistry, 2021 - nature.com
Precious metal complexes with the d 6 valence electron configuration often exhibit
luminescent metal-to-ligand charge transfer (MLCT) excited states, which form the basis for …

Boosting wide‐range tunable long‐afterglow in 1D metal–organic halide micro/nanocrystals for space/time‐resolved information photonics

B Zhou, G Xiao, D Yan - Advanced Materials, 2021 - Wiley Online Library
Molecular afterglow materials with ultralong‐lived excited states have attracted considerable
interest owing to their promise for light‐emitting devices, optical imaging, and anti …

Janus-type emission from a cyclometalated iron(iii) complex

J Steube, A Kruse, OS Bokareva, T Reuter… - Nature Chemistry, 2023 - nature.com
Although iron is a dream candidate to substitute noble metals in photoactive complexes,
realization of emissive and photoactive iron compounds is demanding due to the fast …

Accessing photoredox transformations with an iron (III) photosensitizer and green light

A Aydogan, RE Bangle, A Cadranel… - Journal of the …, 2021 - ACS Publications
Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …