Cobalt-catalyzed dehydrogenative functionalization of alcohols: progress and future prospect

I Borthakur, A Sau, S Kundu - Coordination Chemistry Reviews, 2022 - Elsevier
Functionalization of alcohol is a promising field in synthesis for the possible conservation of
fossil-based-feedstocks, since alcohols can be easily obtained from readily available …

Recent advances in C/N-alkylation with alcohols through hydride transfer strategies

M Jafarzadeh, SH Sobhani, K Gajewski… - Organic & Biomolecular …, 2022 - pubs.rsc.org
This review highlights the most recent reports in three powerful and ever-growing fields of
borrowing hydrogen, acceptorless dehydrogenative coupling, and base-mediated hydride …

Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation

X Liu, L Huang, Y Ma, G She, P Zhou, L Zhu… - Nature …, 2024 - nature.com
A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …

Iron-catalyzed α-methylation of ketones using methanol as the C1 source under photoirradiation

B Emayavaramban, P Chakraborty, P Dahiya… - Organic …, 2022 - ACS Publications
A mild, environmentally benign approach for α-methylation of ketones utilizing methanol as
the C1 source under visible light has been developed. The reaction conditions were …

Selective catalytic synthesis of α-alkylated ketones and β-disubstituted ketones via acceptorless dehydrogenative cross-coupling of alcohols

D Bhattacharyya, BK Sarmah, S Nandi… - Organic …, 2021 - ACS Publications
Herein, a phosphine-free pincer ruthenium (III) catalyzed β-alkylation of secondary alcohols
with primary alcohols to α-alkylated ketones and two different secondary alcohols to β …

Reversal of Regioselectivity in Asymmetric C− H Bond Annulation with Bromoalkynes under Cobalt Catalysis

A Das, R Mandal, HS Ravi Sankar… - Angewandte …, 2024 - Wiley Online Library
Metal‐catalyzed asymmetric C− H bond annulation strategy offers a versatile platform,
allowing the construction of complex P‐chiral molecules through atom‐and step‐economical …

Hydrogen autotransfer with alcohols for alkylations

N Joly, S Gaillard, A Poater, JL Renaud - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Despite the advancements enabled by organometallic complexes in organic synthesis,
which have led to innovative transformations and tackled issues related to waste and atom …

Silver Supported Nanoparticles on [Mg4Al‐LDH] as an Efficient Catalyst for the α‐Alkylation of Nitriles, Oxindoles and Other Carboxylic Acid Derivatives with Alcohols

L Izquierdo‐Aranda, R Adam… - …, 2023 - Wiley Online Library
An efficient heterogeneous silver‐catalyzed α‐alkylation of nitriles and oxindoles using
alcohols via borrowing hydrogen strategy has been developed for the first time. The active …

Mechanistic Investigations on Cp*CoIII-Catalyzed Quinoline Transfer Hydrogenation with Formic Acid

N Garg, P Dahiya, S Mallet-Ladeira, R Poli… - ACS …, 2024 - ACS Publications
The mechanism of the quinoline transfer hydrogenation (TH) by aqueous HCOOH under the
action of [Cp* Co (quinNH2) I]+(A*; quinNH2= 8-aminoquinoline) has been investigated by a …

Facile Benzylic Alkylation of Arenes with Alcohols by Catalysis with Spirocyclic NHC IrIII Pincer Complex

KL Dai, QL Chen, WP Xie, K Lu, ZB Yan… - Angewandte Chemie …, 2022 - Wiley Online Library
A facile benzylic alkylation of indenes and other arenes was developed from readily
available primary and secondary alcohols using our newly investigated CCC pincer IrIII …