The excellent birefringent materials are needed for optical systems. Herein, we reported a
new compound, the first tin borate chloride, Sn2B5O9Cl (SBOC) with a large birefringence …

Borosulfates are oxoanionic compounds consisting of condensed sulfur‐and boron‐
centered tetrahedra. Hitherto, they were mostly achieved from solvothermal syntheses in …

The impact of the surrounding ligand field is successfully exploited in the case of Eu2+ to
tune the emission characteristics of inorganic photoactive materials with potential …

Despite borate‐sulfates composed of isolated borate and sulfate groups have been
discovered for more than one century, borosulfates of B‐O‐S bonding have not been …

Sulfates have long been ignored as nonlinear optical materials over the past decades. Here
we report a new sulfate deep-ultraviolet nonlinear optical material Li8NaRb3 (SO4) 6· 2H2O …

Finding a deep-ultraviolet (deep-UV, λ< 200 nm) nonlinear optical (NLO) crystal is vital to a
number of advanced optical technologies, yet it remains a great challenge. Herein, we report …

Borates provide an excellent platform for investigating the optical nonlinearity and linearity of
crystals as photoelectric functional materials. In our work, borate derivatives with isolated …

Two unprecedented metal borate-iodates, Sr [B (OH) 4](IO3)(SBIO) and Li4Sr5 [B12O22
(OH) 4](IO3) 2 (LSBIO), were synthesized via the strategy of introducing (IO3)− into borates …

High proton conductivity is reported for unhumidified ammonium borosulfate, NH4 [B (SO4)
2], a solid acid coordination polymer that contains 1D, hydrogen‐bonded NH4+··· 1∞[B …

The first mixed alkali metal borosulfate compound, Li2NaB3S2O12 (LNBSO), which contains
[BO3] groups, was designed and synthesized by using a high boron-to-sulfur ratio strategy …