Iron in Organometallic Transformations: A Sustainable Substitute for Noble Metals

R Kumar, T Tewari, SH Chikkali - ChemCatChem, 2024 - Wiley Online Library
Transition metal catalysis plays a pivotal role in chemical synthesis. Noble metals often grab
significant attention in organometallic catalysis due to their high reactivity. However, the …

Catalytic hydroformylation of alkenes to branched aldehydes promoted by water on Rh nanoclusters-anchored porous triphenylphosphine frameworks

D Wang, G Zeng, J Fang, H Li, H Chen, J Ma… - Chemical Engineering …, 2024 - Elsevier
The highly selective catalytic hydroformylation of alkenes to produce aldehydes is an
important reaction in the chemical industry. While the recycling of the currently used …

Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols

M Markwitz, K Łyczek, Q Bu, K Kuciński - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
In this study, we introduce a method for directly synthesizing various siloxanes from
hydrosilanes and silanols under ambient conditions. This process relies on the use of …

Iron‐Catalyzed Alkoxylation, Dehydrogenative‐Polymerization and Tandem Hydrosilylative‐Alkoxylation

A Sen, R Kumar, T Tewari, RG Gonnade… - … A European Journal, 2023 - Wiley Online Library
Alkoxylation, hydrosilylative‐alkoxylation, and dehydrogenative‐polymerization are some of
the most widely used transformations in synthetic chemistry. However, these transformations …

Site-Selective Magnesiation of Multifluorinated Arenes Catalyzed by Rhodium–Aluminum Bimetallic Complexes

I Fujii, K Semba, Y Nakao - ACS Catalysis, 2024 - ACS Publications
We report the site-selective C–F magnesiation of multifluorinated arenes catalyzed by Rh–Al
bimetallic complexes to prepare synthetically important fluorine-containing …

Iron-catalysed highly selective hydroalkoxycarbonylation of alkynes using CO as C1 source

T Tewari, R Kumar, SH Chikkali - Catalysis Science & Technology, 2023 - pubs.rsc.org
Though precious and rare, late-transition metals have been extensively used in metal-
catalysed carbonylation reactions in organic transformations. On the other hand, base …

Copper-catalyzed syn-hydroformylation of alkynes with silane and N, N-dimethylformamide dimethylacetal

M Huai, L Chen, W Dong, W Wang, Z Qin… - Organic & …, 2024 - pubs.rsc.org
A copper-catalyzed syn-hydrocarbonization of internal alkynes with N, N-dimethylformamide
dimethylacetal and silanes has been disclosed that offers an efficient and expedient access …

Ambient Pressure Hydroformylation – A Key Step to Meso‐Alkyl BODIPYs

L Miller, F Bauer, B Breit - European Journal of Organic …, 2024 - Wiley Online Library
Herein, a highly efficient five‐step reaction sequence to meso‐alkyl BODIPYs is presented.
In our previous work, the hydroformylation of terminal alkenes was used to generate an …

[PDF][PDF] Синтез стиролов, модифицированных ароматическими флуорофорами, и полимеров на их основе: диссертация на соискание ученой степени …

ЕМ Зен - 2024 - elar.urfu.ru
Развитие химии стиролов, модифицированных флуорофорами, является актуальным
направлением исследований, имеющим своей целью создание новых полимерных …