The conversion of vast low-value saturated hydrocarbons into valuable chemicals is of great
interest. Thanks to the progression of organometallic and coordination chemistry, transition …

In recent years, great improvements have been made on palladium‐catalyzed radical
reactions. Emerging elegant methodologies of radical involved palladium‐catalyzed …

Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

Carbon monoxide is an abundant and cost-efficient C1 building block for the carbonylation
industry. Transition-metal-catalyzed oxidative C–H/C (X)–H carbonylation with CO provides …

The control of reaction selectivity is a core of organic synthesis, which requires the rational
design of the catalytic system. Carbonylation reactions involving CO, such as …

Abstract Electrochemical oxidative C− H/N− H activations with isocyanides have been
realized with a versatile cobalt catalyst. The widely applicable cobalt catalysis manifold …

Adamantane derivatives have diverse applications in the fields of medicinal chemistry,
catalyst development and nanomaterials, owing to their unique structural, biological and …

Petroleum hydrocarbons are our major energy source and an important feedstock for the
chemical industry. With the exception of combustion, the deep conversion of chemically inert …

Abstract The 1, 4‐palladium shift strategy allows the functionalization of remote C− H bonds
that are difficult to reach directly. Reported here is a domino reaction proceeding by C (sp3) …

A continuous-flow Pd-catalyzed oxidative carbonylation protocol utilizing CO and O2 gas for
the synthesis of carbonylated heterocycles is described. The optimization of temperature …