π-Bonding and the lone pair effect in multiple bonds involving heavier main group elements: developments in the new millennium
RC Fischer, PP Power - Chemical reviews, 2010 - ACS Publications
This review is essentially an update of one entitled “π-Bonding and The Lone Pair Effect in
Multiple Bonds Between Heavier Main Group Elements” which was published more than 10 …
Multiple Bonds Between Heavier Main Group Elements” which was published more than 10 …
Functional disilenes in synthesis
A Rammo, D Scheschkewitz - Chemistry–A European Journal, 2018 - Wiley Online Library
Functionalized disilenes are valuable auxiliary tools in preparative chemistry. In the
following review the various synthetic potential of disilenes as precursors is presented. Upon …
following review the various synthetic potential of disilenes as precursors is presented. Upon …
Synthesis of a Donor‐Stabilized Silacyclopropan‐1‐one
R Rodriguez, T Troadec, D Gau… - Angewandte Chemie …, 2013 - infona.pl
As intriguing as the Bermuda Triangle: The synthesis and characterization of an isolable
silacyclopropan‐1‐one (see structure; red O, blue N, green Si, yellow P) was made possible …
silacyclopropan‐1‐one (see structure; red O, blue N, green Si, yellow P) was made possible …
Regioselective annulation of propargyl alcohols with ambident-enols: A Ca (II)-catalyzed trisubstituted benzochromene synthesis
Highly regioselective, 6-endo cyclization between propargyl alcohols and ambident enols
such as naphthols, 4-hydroxy coumarin, cyclohexane-1, 3-dione, 5, 5-dimethylcyclohexane …
such as naphthols, 4-hydroxy coumarin, cyclohexane-1, 3-dione, 5, 5-dimethylcyclohexane …
An Isolable Potassium Salt of a Borasilene–Chloride Adduct
Y Suzuki, S Ishida, S Sato, H Isobe… - Angewandte Chemie …, 2017 - Wiley Online Library
Among the variety of isolable compounds with multiple bonds involving silicon, examples of
compounds that contain silicon–boron double bonds (borasilenes) still remain relatively …
compounds that contain silicon–boron double bonds (borasilenes) still remain relatively …
New perspectives for “non-classical” molecules: heavy [1.1. 1] propellanes of group 14
D Nied, F Breher - Chemical Society Reviews, 2011 - pubs.rsc.org
Heavy analogues of hydrocarbons intrigue chemists for a number of reasons, not least
because they are often fundamentally different from their carbon counterparts and have …
because they are often fundamentally different from their carbon counterparts and have …
Donor–Acceptor Adducts of a 1, 3‐Disila‐2‐oxyallyl Zwitterion
MJ Cowley, V Huch… - Chemistry–A European …, 2014 - Wiley Online Library
In the presence of a Lewis acid or base, cyclotrisilene cSi3Tip4 (Tip= 2, 4, 6‐
triisopropylphenyl) reacts with CO to form stable adducts of a 1, 3‐disila‐2‐oxyallyl …
triisopropylphenyl) reacts with CO to form stable adducts of a 1, 3‐disila‐2‐oxyallyl …
Stable germenolates and germenes with exocyclic structures
M Haas, M Leypold, D Schnalzer, A Torvisco… - …, 2015 - ACS Publications
The first germenolates with exocyclic structures [(Me3Si) 2Ge (Si2Me4) 2GeC (R) O]− K+
(5a: R= Mes; 5b: o-Tol; 5c: 1-Ad) were synthesized by the reaction of the corresponding …
(5a: R= Mes; 5b: o-Tol; 5c: 1-Ad) were synthesized by the reaction of the corresponding …
Control of the ambident reactivity of the nitrite ion
In previous studies, it was reported that a neighbouring equatorial ester group is essential
for a good yield of nitrite-mediated triflate inversion, whereas with neighbouring benzyl ether …
for a good yield of nitrite-mediated triflate inversion, whereas with neighbouring benzyl ether …
Synthesis of Silenyllithiums Li(R′3Si)SiC(SiR3)(1-Ad) via Transient Silyne–Silylidene Intermediates
L Zborovsky, R Dobrovetsky… - Journal of the …, 2012 - ACS Publications
The first two lithium silenides, Li (t Bu2MeSi) Si C (SiMe t Bu2)(1-Ad)(1) and Li (t BuMe2Si)
Si C (SiMe t Bu2)(1-Ad)(2) were prepared by THF addition to the corresponding lithium …
Si C (SiMe t Bu2)(1-Ad)(2) were prepared by THF addition to the corresponding lithium …