Platonic and Archimedean solids in discrete metal-containing clusters

XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Biologically active molecules with a “light switch”

G Mayer, A Heckel - Angewandte Chemie International Edition, 2006 - Wiley Online Library
Biologically active compounds which are light‐responsive offer experimental possibilities
which are otherwise very difficult to achieve. Since light can be manipulated very precisely …

Synthesis of 3d Metallic Single-Molecule Magnets

G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Structural and functional evolution of metallacrowns

G Mezei, CM Zaleski, VL Pecoraro - Chemical reviews, 2007 - ACS Publications
In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism

YK Deng, HF Su, JH Xu, WG Wang… - Journal of the …, 2016 - ACS Publications
In search of functional molecular materials and the study of their formation mechanism, we
report the elucidation of a hierarchical step-by-step formation from monomer (Mn) to …

Synthesis, structure, and magnetic properties of a large lanthanide–transition‐metal single‐molecule magnet

CM Zaleski, EC Depperman, JW Kampf… - Angewandte Chemie …, 2004 - Wiley Online Library
The chemistry of large lanthanide clusters has long been a focus of coordination chemists
due to the unique properties conferred upon molecules that have f electrons. Recently, large …

The coordination chemistry of pyridyl oximes

CJ Milios, TC Stamatatos, SP Perlepes - Polyhedron, 2006 - Elsevier
The coordination chemistry of pyridyl oximes is reviewed. Simple pyridyl oximes have the
general formula (py) C (R) NOH, where py is a pyridyl group (2-, 3-or 4-) attached to the …

Structural motifs and topological representation of Mn coordination clusters

GE Kostakis, AM Ako, AK Powell - Chemical Society Reviews, 2010 - pubs.rsc.org
Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

MnII Coordination Polymers Based on Bi-, Tri-, and Tetranuclear and Polymeric Chain Building Units: Crystal Structures and Magnetic Properties

LF Ma, ML Han, JH Qin, LY Wang, M Du - Inorganic Chemistry, 2012 - ACS Publications
Five new MnII coordination polymers, namely [Mn2 (tbip) 2 (bix)](1),[Mn3 (tbip) 3 (bix)
2](2),[Mn3 (tbip) 2 (Htbip) 2 (bib) 2]· 4H2O (3),[Mn4 (tbip) 4 (bbp) 2 (H2O) 2](4), and [Mn4 …