In recent years, researchers have shifted their focus towards investigating the redox
properties of ancillary ligand backbones for small‐molecule activation. Several metal …

Currently, more than 55 million people live with dementia worldwide, and there are nearly
10 million new cases every year. Alzheimer's disease (AD) is the most common …

In the past decade, the use of redox-active ligands has emerged as a promising strategy to
improve catalyst selectivity, efficiency, and stability in electroassisted H+ and CO2 …

In this study, we report a pair of electrocatalysts for the hydrogen evolution reaction (HER)
based on the noninnocent ligand diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2 …

Three ABAB-type cobalt meso-tetraarylporphyrins with fluorine (F-CoPor), acetic acid (AC-
CoPor), and cyanoacetic acid (CN-CoPor) groups at the para-positions of phenyl rings at the …

Electrocatalytic hydrogen gas production is considered a potential pathway towards carbon‐
neutral energy sources. However, the development of this technology is hindered by the lack …

The use of non–precious metals for electrocatalytic hydrogen reaction (HER) is particularly
important for energy conservation and environmental protection. In this work, three new …

Nitrogen‐doped carbon dots were used as photosensitizers for H2 evolution in the presence
of a series of mononuclear thiosemicarbazone nickel complexes. The catalysts were …

Experimental magnetic studies performed on the [{CuLX} 2] system (HL= pyridine-2-
carbaldehyde thiosemicarbazone, X= Cl−, Br−, I−) point to the larger electronegativity in X …

Enzymes and heterogenous catalysts for CO2 reduction reactions (CO2RR) use secondary
interactions between metal sites and protein-derived coordination spheres to control the …