[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials

E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

Octacyanidorhenate (V) ion as an efficient linker for hysteretic two‐step iron (II) spin crossover switchable by temperature, light, and pressure

S Chorazy, T Charytanowicz… - Angewandte Chemie …, 2020 - Wiley Online Library
A two‐step hysteretic FeII spin crossover (SCO) effect was achieved in programmed layered
Cs {[Fe (3‐CNpy) 2][Re (CN) 8]}⋅ H2O (1)(3‐CNpy= 3‐cyanopyridine) assembly consisting …

Bistable molecular materials with dynamic structures

ZS Yao, Z Tang, J Tao - Chemical communications, 2020 - pubs.rsc.org
The development of molecular materials whose physical properties can be switched
between different states has attracted significant attention for their potential application in …

Hysteretic Four‐Step Spin Crossover within a Three‐Dimensional Porous Hofmann‐like Material

JE Clements, JR Price, SM Neville… - Angewandte …, 2016 - Wiley Online Library
Materials that display multiple stepped spin crossover (SCO) transitions with accompanying
hysteresis present the opportunity for ternary, quaternary, and quinary electronic switching …

Switchable cobalt coordination polymers: Spin crossover and valence tautomerism

O Drath, C Boskovic - Coordination Chemistry Reviews, 2018 - Elsevier
Electronically labile, or switchable, cobalt coordination polymers exhibit reversible spin
crossover (SCO) or valence tautomeric (VT) transitions upon the application of an external …

Spin state switching in 2, 6-bis (pyrazol-3-yl) pyridine (3-bpp) based Fe (II) complexes

GA Craig, O Roubeau, G Aromi - Coordination Chemistry Reviews, 2014 - Elsevier
The area of spin crossover (SCO) attracts interest both on a fundamental level and in terms
of potential applications for compounds displaying this phenomenon. A few families of Fe (II) …

Hysteretic Spin Crossover with High Transition Temperatures in Two Cobalt (II) Complexes

YC Sun, FL Chen, KJ Wang, Y Zhao, HY Wei… - Inorganic …, 2023 - ACS Publications
Cooperative spin crossover transitions with thermal hysteresis loops are rarely observed in
cobalt (II) complexes. Herein, two new mononuclear cobalt (II) complexes with hysteretic …

Anion effects on spin crossover systems: from supramolecular chemistry to magnetism

SZ Zhao, HW Zhou, CY Qin, HZ Zhang… - … A European Journal, 2023 - Wiley Online Library
The field of anion supramolecular chemistry has received more and more attention in recent
years. Anions with diverse types and geometries have been widely used for the synthesis of …

Reversible on–off switching of the hysteretic spin crossover in a cobalt (II) complex via crystal to crystal transformation

D Shao, L Shi, FX Shen, XQ Wei, O Sato… - Inorganic …, 2019 - ACS Publications
Reversible controlling and switching of magnetic bistability remains relatively difficult. Here,
reversible on–off switching of a hysteretic spin transition in a CoII complex via a single …