Inorganic Metal Thiocyanates
MJ Cliffe - Inorganic Chemistry, 2024 - ACS Publications
Metal thiocyanates were some of the first pseudohalide compounds to be discovered and
adopt a diverse range of structures. This review describes the structures, properties, and …
adopt a diverse range of structures. This review describes the structures, properties, and …
Ion transport mechanism in anhydrous lithium thiocyanate LiSCN part II: frequency dependence and slow jump relaxation
M Joos, M Conrad, I Moudrakovski… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific aspects of the Li+ cation conductivity of anhydrous Li (SCN) are investigated, in
particular the high migration enthalpy of lithium vacancies. Close inspection of impedance …
particular the high migration enthalpy of lithium vacancies. Close inspection of impedance …
Ion transport mechanism in anhydrous lithium thiocyanate LiSCN Part I: ionic conductivity and defect chemistry
This work reports on the ion transport properties and defect chemistry in anhydrous lithium
thiocyanate Li (SCN), which is a pseudo-halide Li+ cation conductor. An extensive doping …
thiocyanate Li (SCN), which is a pseudo-halide Li+ cation conductor. An extensive doping …
On the crystal structures of lithium thiocyanate monohydrate LiSCN⋅ 1 H2O and the phase diagram LiSCN–H2O
Hydration of anhydrous LiSCN by stoichiometric amounts of water vapor leads to the
formation of LiSCN⋅ 1 H 2 O. At room temperature, LiSCN⋅ 1 H 2 O crystallizes in the …
formation of LiSCN⋅ 1 H 2 O. At room temperature, LiSCN⋅ 1 H 2 O crystallizes in the …
Synthesis and characterisation of two lithium-thiocyanate solvates with tetrahydrofuran: Li [SCN]· THF and Li [SCN]· 2THF
Li [SCN]· THF and Li [SCN]· 2THF can be obtained from solutions of anhydrous Li [SCN] in
tetrahydrofuran (C4H8O, THF). Both compounds are very hygroscopic and slowly …
tetrahydrofuran (C4H8O, THF). Both compounds are very hygroscopic and slowly …
Lithium ion transport in water-containing Li (SCN) over a wide compositional range: From water doping to hydration
This work explores the Li+ cation transport mechanisms in the system Li (SCN)· x H 2 O,
complementary to our previous studies on crystal structures and hydration properties of …
complementary to our previous studies on crystal structures and hydration properties of …
Ion transport mechanism in anhydrous lithium thiocyanate LiSCN part III: charge carrier interactions in the premelting regime
In lithium thiocyanate Li (SCN), the temperature regime below the melting point (274° C) is
characterized by excess conductivities over the usual Arrhenius behavior (premelting …
characterized by excess conductivities over the usual Arrhenius behavior (premelting …
Synthesis, Crystal Structure and Properties of a new Hydrate of Manganese Thiocyanate with the Composition Mn(NCS)2(H2O)2
C Näther, I Jess, C Krebs… - … für anorganische und …, 2022 - Wiley Online Library
The reaction of Mn (NCS) 2 with 3‐cyanopyridine in water accidentally leads to the formation
of single crystals of Mn (NCS) 2 (H2O) 2 (1). If the synthesis is performed without 3 …
of single crystals of Mn (NCS) 2 (H2O) 2 (1). If the synthesis is performed without 3 …