Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Supramolecular catalysis—the assembly of catalyst species by harnessing multiple weak
intramolecular interactions—has, until recently, been dominated by enzyme-inspired …

In the last decade there have been numerous advances in the area of rhodium-catalyzed
hydroformylation, such as highly selective catalysts of industrial importance, new insights …

In the past few years, supramolecular chemistry has led to new approaches in
homogeneous catalysis. While host-guest chemistry had already found applications in …

N, N′-Di (S-phenylethyl)-2-amino-4-iminopent-2-ene, S, S-nacnac CH (Me) PhH, 1a, and
N, N′-dibenzyl-2-amino-4-iminopent-2-ene, nacnac BnH, 1b, react with ZnEt2 to form the …

The first palladium catalyst system that allows the direct allylation of indoles with allylic
alcohols as substrates with water being the only byproduct is presented. The application of …

The use of non covalent supramolecular ligand–ligand and ligand–substrate interactions in
transition metal-catalysed transformations is a new, rapidly emerging area of research. Non …

d-Glucose has been identified as an efficient C1 synthon in the synthesis of benzimidazoles
from o-phenylenediamines via an oxidative cyclization strategy. Isotopic studies with 13C6-d …

Hydroamidation of olefins constitutes an ideal, atom-efficient method to prepare carboxylic
amides from easily available olefins, CO, and amines. So far, aliphatic amines are not …

The development of chelating diphosphine ligands has been a prolific research area for
several decades, but quite surprisingly, from the plethora of diphosphines that are currently …