Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

A general formulation is presented to model photodissociation processes in which internal
conversion is followed by unimolecular dissociation over an exit barrier; this classification of …

Recent experimental and computational advances have heralded huge progress in the
range and the detail of the database pertaining to photoinduced C–H bond fission …

The photodissociation of jet-cooled HCCH molecules following excitation to their S 1 state
has been investigated further, at a number of wavelengths in the range 205–220 nm, using …

Formation of fluorocarbon polymer films with a linear (CF2–CF2) n molecular structure
similar to polytetrafluoroethylene, PTFE is described by a hot filament chemical vapor …

H (Rydberg) atom photofragment translational spectroscopy has been used to study the
photodissociation dynamics of jet-cooled formic acid molecules following excitation to their …

N, N-dimethylformamide, HCON (CH 3) 2, is a useful model compound for investigating the
peptide bond photofragmentation dynamics. We report data from a comprehensive …

Potential energy surfaces of the HFCO dissociation to H+ FCO and F+ HCO in the lowest
three electronic states (S0, S1, and T1) have been investigated with ab initio molecular …

The time-of-flight spectrum of the H atoms resulting from photodissociation of gas phase
HFCO molecules at 243.12 nm indicates a role for secondary photolysis of HCO () fragments …

Direct ab-initio dynamics calculations have been applied to the photodissociation of the
HFCO molecule on the potential energy surface at the triplet state in order to elucidate its …