This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

This review highlights and summarizes various optically active porphyrin and
phthalocyanine molecules prepared using a wide range of structural modification methods …

The remarkable properties of both phthalocyanines and porphyrins as individual building
blocks have motivated the synthesis and study of homo-and heterobinuclear conjugates as …

Porphyrin macrocycles have been the subject of intense study in the last century because
they are widely distributed in nature, usually as metal complexes of either iron or …

Porphyrin atropisomerism, which arises from restricted σ‐bond rotation between the
macrocycle and a sufficiently bulky substituent, was identified in 1969 by Gottwald and …

Porphyrin arrays are an important class of compounds to study interporphyrin electronic
interactions that are crucial in determining the rates of energy transfer and electron transfer …

Reversible homolytic dissociation of the bis (pyrimidinenorcorrole) σ‐dimer was elucidated
by means of variable temperature ESR and 1H NMR spectroscopy, mass spectrometry, and …

Supramolecular chirality, being an intelligent combination of supramolecular chemistry and
chiral science, plays a decisive role in the functioning of various natural assemblies and has …

Dimesitylnorcorrolatonickel (II) was hydrogenated under mild conditions (room temperature,
1 atm H2, THF solution, 5 min.) in the presence of Raney nickel to yield nonaromatic …

Dioxaporphyrin was synthesized for the first time by a nucleophilic aromatic substitution
reaction of a nickel bis (α, α′‐dibromodipyrrin) complex with benzaldoxime, followed by an …