Hydrogen/deuterium exchange in mass spectrometry

Y Kostyukevich, T Acter, A Zherebker… - Mass Spectrometry …, 2018 - Wiley Online Library
The isotopic exchange approach is in use since the first observation of such reactions in
1933 by Lewis. This approach allows the investigation of the pathways of chemical and …

Formula assignment algorithm for deuterium-labeled ultrahigh-resolution mass spectrometry: implications of the formation mechanism of halogenated disinfection …

QL Fu, M Fujii, A Watanabe, E Kwon - Analytical Chemistry, 2022 - ACS Publications
Ultrahigh-resolution mass spectrometry (UHR-MS) coupled with isotope labeling has
attracted significant attention in elucidating the mechanisms of the transformation of …

Antiviral activity of natural humic substances and shilajit materials against HIV-1: Relation to structure

YV Zhernov, AI Konstantinov, A Zherebker… - Environmental …, 2021 - Elsevier
Natural products, such as humic substances (HS) and shilajit, are known to possess antiviral
activity. Humic-like components are often called as carriers of biological activity of shilajit …

Optical properties of soil dissolved organic matter are related to acidic functions of its components as revealed by fractionation, selective deuteromethylation, and …

A Zherebker, E Shirshin, A Rubekina… - … science & technology, 2020 - ACS Publications
The goal of this study was to establish a relationship between the optical properties of soil
dissolved organic matter (DOM) and acidic functions carried out by its individual …

Fungal Laccase-Catalyzed Oxidation of Naturally Occurring Phenols for Enhanced Germination and Salt Tolerance of Arabidopsis thaliana: A Green Route for …

JY Cha, TW Kim, JH Choi, KS Jang… - Journal of agricultural …, 2017 - ACS Publications
Fungal laccases have been highlighted as a catalytic tool for transforming phenols. Here we
demonstrate that fungal laccase-catalyzed oxidations can transform naturally occurring …

Mass difference matching unfolds hidden molecular structures of dissolved organic matter

C Simon, K Dührkop, D Petras, VN Roth… - Environmental …, 2022 - ACS Publications
Ultrahigh-resolution Fourier transform mass spectrometry (FTMS) has revealed
unprecedented details of natural complex mixtures such as dissolved organic matter (DOM) …

From green chemistry and nature-like technologies towards ecoadaptive chemistry and technology

IV Perminova - Pure and Applied Chemistry, 2019 - degruyter.com
Nature-like technologies can be considered as a logical development of green chemistry
principles implemented to design novel materials and processes aimed at mimicking and …

Examination of molecular space and feasible structures of bioactive components of humic substances by FTICR MS data mining in ChEMBL database

AA Orlov, A Zherebker, AA Eletskaya, VS Chernikov… - Scientific Reports, 2019 - nature.com
Humic substances (HS) are complex natural mixtures comprising a large variety of
compounds produced during decomposition of decaying biomass. The molecular …

Promotion of the catalytic polymerization of hydroquinone towards humic-like substances by graphitic carbon nitride

MMM Ahmed, YT Liu, S Venkatesan, MC Wu… - Journal of …, 2023 - Elsevier
The utilization of graphitic carbon nitride (C 3 N 4) to enhance the oxidative polymerization
of hydroquinone (HQ) within manganese dioxide (MnO 2) systems was investigated. C 3 N …

Enumeration of carboxyl groups carried on individual components of humic systems using deuteromethylation and Fourier transform mass spectrometry

A Zherebker, Y Kostyukevich, A Kononikhin… - Analytical and …, 2017 - Springer
Here, we report a novel approach to enumeration of carboxylic groups carried by individual
molecules of humic substances using selective chemical modification and isotopic labeling …