Control of selectivity in palladium (II)-catalyzed oxidative transformations of allenes

B Yang, Y Qiu, JE Bäckvall - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Oxidation reactions play a central role in organic synthesis, and it is highly
desirable that these reactions are mild and occur under catalytic conditions. In Nature …

Palladium-catalyzed oxidative dehydrogenative carbonylation reactions using carbon monoxide and mechanistic overviews

C Zhu, J Liu, MB Li, JE Bäckvall - Chemical Society Reviews, 2020 - pubs.rsc.org
Carbon monoxide, which is an abundant and inexpensive carbonyl source, has been widely
applied to synthesize carbonyl-containing compounds, for example ketones, esters, and …

An update on oxidative C–H carbonylation with CO

Y Liu, YH Chen, H Yi, A Lei - ACS Catalysis, 2022 - ACS Publications
Carbonyl derivatives widely exist in pharmaceuticals, agricultural chemicals, materials, and
natural products. Developing novel, efficient, and green carbonylation methods represent …

Palladium-Catalyzed Carbonylations: Application in Complex Natural Product Total Synthesis and Recent Developments

HS Sims, M Dai - The Journal of Organic Chemistry, 2023 - ACS Publications
Carbon monoxide is a cheap and abundant C1 building block that can be readily
incorporated into organic molecules to rapidly build structural complexity. In this Perspective …

The lower the better: Efficient carbonylative reactions under atmospheric pressure of carbon monoxide

Q Tian, X Yin, R Sun, Y Li - Coordination Chemistry Reviews, 2023 - Elsevier
Carbon monoxide is an indispensable C1 building block that has been recognized as a
potent feedstock for synthesizing carbonyl-containing molecules. Carbonylative reactions …

Electrochemical Palladium‐Catalyzed Oxidative Carbonylation‐Cyclization of Enallenols

J Zhang, B Das, O Verho, JE Bäckvall - Angewandte Chemie, 2022 - Wiley Online Library
Herein, we report an electrochemical oxidative palladium‐catalyzed carbonylation‐
carbocyclization of enallenols to afford γ‐lactones and spirolactones, which proceeds with …

Advances in palladium‐catalyzed cascade cyclizations

J Biemolt, E Ruijter - Advanced Synthesis & Catalysis, 2018 - Wiley Online Library
The past decades in organic chemistry have witnessed significant improvements in synthetic
efficiency as a result of considerable progress in cascade reactions, tandem reactions, and …

Chemodivergent and diastereoselective synthesis of γ-lactones and γ-lactams: a heterogeneous palladium-catalyzed oxidative tandem process

MB Li, AK Inge, D Posevins… - Journal of the …, 2018 - ACS Publications
A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a
homogeneous/heterogeneous catalysis manifold, setting the stage for the highly …

Palladium‐Catalyzed Cascade Cyclization/Alkynylation Reactions

J Li, S Yang, W Wu, H Jiang - Chemistry–An Asian Journal, 2019 - Wiley Online Library
Palladium‐catalyzed cascade cyclization reactions have witnessed significant
improvements in recent years. Among them, palladium‐catalyzed cascade cyclization …

Efficient heterogeneous copper-catalyzed Alder-ene reaction of allenynamides to pyrrolines

Z Zheng, L Deiana, D Posevins, AA Rafi, K Zhang… - ACS …, 2022 - ACS Publications
Herein, we describe an efficient nanocopper-catalyzed Alder-ene reaction of allenynamides.
The copper nanoparticles were immobilized on amino-functionalized microcrystalline …