Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

C–H activation

T Rogge, N Kaplaneris, N Chatani, J Kim… - Nature Reviews …, 2021 - nature.com
Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Traditional and sustainable approaches for the construction of C–C bonds by harnessing C–H arylation

J Grover, G Prakash, N Goswami, D Maiti - Nature Communications, 2022 - nature.com
Biaryl scaffolds are found in natural products and drug molecules and exhibit a wide range
of biological activities. In past decade, the transition metal-catalyzed C–H arylation reaction …

Sustainable protocols for direct C–H bond arylation of (hetero) arenes

G Albano, A Punzi, MAM Capozzi, GM Farinola - Green Chemistry, 2022 - pubs.rsc.org
Direct C–H bond arylation of (hetero) arenes is a very convenient approach for the synthesis
of a wide variety of molecular targets, including compounds of pharmaceutical interest and π …

Synthesis of medium-sized benzo[b]azocines and benzo[b]azonines by photoinduced 8-/9-endo sulfonyl-cyclization

K Sun, D Zhao, Q Li, S Ni, G Zheng, Q Zhang - Science China Chemistry, 2023 - Springer
An efficient photochemical radical sulfonyl cyclization of designed dienes to medium-sized
benzo [b] azocines and benzo [b] azonines was developed. This chemoselective method …

Biaryl synthesis with arenediazonium salts: cross-coupling, CH-arylation and annulation reactions

FX Felpin, S Sengupta - Chemical Society Reviews, 2019 - pubs.rsc.org
The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

U Dhawa, N Kaplaneris, L Ackermann - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
Transition metal catalyzed C–H activation has surfaced as a powerful tool to improve the
efficacy of molecular synthesis. Last two decades have witnessed a considerable progress …

Aryldiazonium salts in photoredox catalysis–recent trends

SS Babu, P Muthuraja, P Yadav… - Advanced Synthesis & …, 2021 - Wiley Online Library
Aryl diazonium salts are an important class of organic compounds that are now widely used
as arylating agents in photoredox catalysis owing to their lower redox potential, broad …

When metal-catalyzed C–H functionalization meets visible-light photocatalysis

L Guillemard, J Wencel-Delord - Beilstein journal of organic …, 2020 - beilstein-journals.org
While aiming at sustainable organic synthesis, over the last decade particular attention has
been focused on two modern fields, C–H bond activation, and visible-light-induced …