The evolution of spiropyran: fundamentals and progress of an extraordinarily versatile photochrome

L Kortekaas, WR Browne - Chemical Society Reviews, 2019 - pubs.rsc.org
Spiropyrans have played a pivotal role in the emergence of the field of chromism following
their discovery in the early 20th century, with almost ubiquitous use in materials applications …

A modern look at spiropyrans: From single molecules to smart materials

AS Kozlenko, IV Ozhogin, AD Pugachev… - Topics in Current …, 2023 - Springer
Photochromic compounds of the spiropyran family have two main isomers capable of inter-
switching with UV or visible light. In the current review, we discuss recent advances in the …

Design and synthesis of donor–acceptor stenhouse adducts: a visible light photoswitch derived from furfural

S Helmy, S Oh, FA Leibfarth, CJ Hawker… - The Journal of …, 2014 - ACS Publications
The development of an easily synthesized, modular, and tunable organic photoswitch that
responds to visible light has been a long-standing pursuit. Herein we provide a detailed …

Self-assembled Pd (II) barrels as containers for transient merocyanine form and reverse thermochromism of spiropyran

P Howlader, B Mondal, PC Purba… - Journal of the …, 2018 - ACS Publications
Self-assembly of a cis-blocked Pd (II) 90° ditopic acceptor [cis-(tmeda) Pd (NO3) 2](M) with a
tetradentate donor L 1 [benzene-1, 4-di (4-terpyridine)] in 2: 1 molar ratio yielded two …

Light-controlled receptors for environmentally and biologically relevant anions

A Kumar, S Kumar - Chemical Engineering Journal, 2023 - Elsevier
In the past few decades monitoring the concentration of anions has received much interest
due to their role in driving biological processes at low concentrations and toxicity at elevated …

Negatively photochromic organic compounds: Exploring the dark side

S Aiken, RJL Edgar, CD Gabbutt, BM Heron… - Dyes and …, 2018 - Elsevier
The last few years have seen an explosion of interest in traditional photochromic systems
not only for their applications in variable transmission devices, which continues to attract …

Merocyanine dyes: synthesis, structure, properties and applications

AV Kulinich, AA Ishchenko - Russian Chemical Reviews, 2009 - iopscience.iop.org
Key approaches to the synthesis of merocyanine dyes are summarised. The dependence of
the dye properties on their chemical structure, the solvent nature and the aggregation type is …

Digital processing with a three-state molecular switch

FM Raymo, S Giordani, AJP White… - The Journal of organic …, 2003 - ACS Publications
Certain molecular switches respond to input stimulations producing detectable outputs. The
interplay of these signals can be exploited to reproduce basic logic operations at the …

Ultrafast bidirectional photoswitching of a spiropyran

J Buback, M Kullmann, F Langhojer… - Journal of the …, 2010 - ACS Publications
We report on bidirectional photochemical switching of 6, 8-dinitro-1′, 3′, 3′-
trimethylspiro [2 H-1-benzopyran-2, 2′-indoline](6, 8-dinitro-BIPS) between the ring-closed …

Novel polychromogenic fluorine-substituted spiropyrans demonstrating either uni-or bidirectional photochromism as multipurpose molecular switches

AD Pugachev, IV Ozhogin, NI Makarova… - Dyes and …, 2022 - Elsevier
Novel photochromic spiropyrans (SPPs) of the indoline series with fluorine substituents and
cationic fragments or formyl groups at positions 6′ and 8′ of the 2 H-chromene moiety …