Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …

S Daliran, AR Oveisi, Y Peng… - Chemical Society …, 2022 - pubs.rsc.org
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

Catalysis and photocatalysis by metal organic frameworks

A Dhakshinamoorthy, Z Li, H Garcia - Chemical Society Reviews, 2018 - pubs.rsc.org
Metal organic frameworks (MOFs) are a class of porous crystalline materials that feature a
series of unique properties, such as large surface area and porosity, high content of …

Imaging defects and their evolution in a metal–organic framework at sub-unit-cell resolution

L Liu, Z Chen, J Wang, D Zhang, Y Zhu, S Ling… - Nature …, 2019 - nature.com
Defect engineering of metal–organic frameworks (MOFs) offers promising opportunities for
tailoring their properties to specific functions and applications. However, determining the …

The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Electronic structure modeling of metal–organic frameworks

JL Mancuso, AM Mroz, KN Le, CH Hendon - Chemical reviews, 2020 - ACS Publications
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …

Synthesis, characterization and application of defective metal–organic frameworks: current status and perspectives

W Xiang, Y Zhang, Y Chen, C Liu, X Tu - Journal of Materials Chemistry …, 2020 - pubs.rsc.org
Defects are now recognized to be a useful tool in tailoring the properties of metal–organic
frameworks (MOFs). The introduction of missing linker and cluster defects into MOFs …

Defective metal‐organic frameworks

S Dissegna, K Epp, WR Heinz, G Kieslich… - Advanced …, 2018 - Wiley Online Library
The targeted incorporation of defects into crystalline matter allows for the manipulation of
many properties and has led to relevant discoveries for optimized and even novel …

Hierarchically porous zirconium-based metal–organic frameworks for rapid adsorption and enrichment of sulfonamide antibiotics

L Han, P Qin, M Li, D Li, M Mu, Y Gao, S Zhu… - Chemical engineering …, 2023 - Elsevier
Due to serious risk to human health and eco-environmental security, antibiotics in water and
foods received considerable concern. Herein, a series of stable hierarchically porous …