Metabolic engineering of Cupriavidus necator H16 for sustainable biofuels from CO2

J Panich, B Fong, SW Singer - Trends in Biotechnology, 2021 - cell.com
Decelerating global warming is one of the predominant challenges of our time and will
require conversion of CO 2 to usable products and commodity chemicals. Of particular …

Hemoprotein catalyzed oxygenations: P450s, UPOs, and progress toward scalable reactions

G Grogan - JACS Au, 2021 - ACS Publications
The selective oxygenation of nonactivated carbon atoms is an ongoing synthetic challenge,
and biocatalysts, particularly hemoprotein oxygenases, continue to be investigated for their …

Carboxylic acid directed γ-lactonization of unactivated primary C–H bonds catalyzed by Mn complexes: application to stereoselective natural product diversification

A Call, M Cianfanelli, P Besalú-Sala… - Journal of the …, 2022 - ACS Publications
Reactions that enable selective functionalization of strong aliphatic C–H bonds open new
synthetic paths to rapidly increase molecular complexity and expand chemical space …

[HTML][HTML] Paving the way for synthetic C1-metabolism in Pseudomonas putida through the reductive glycine pathway

L Bruinsma, S Wenk, NJ Claassens… - Metabolic …, 2023 - Elsevier
Abstract One-carbon (C1) compounds such as methanol, formate, and CO 2 are alternative,
sustainable microbial feedstocks for the biobased production of chemicals and fuels. In this …

Performance and emission characteristics of second-generation biodiesel with oxygenated additives

S Ahmad, AT Jafry, M Haq, N Abbas, H Ajab, A Hussain… - Energies, 2023 - mdpi.com
Biofuels are environmental friendly renewable fuels, that can be directly used in a diesel
engine. However, a few shortcomings like a higher density, viscosity, a lower calorific value …

Redox metabolism for improving whole-cell P450-catalysed terpenoid biosynthesis

B Nowrouzi, L Rios-Solis - Critical Reviews in Biotechnology, 2022 - Taylor & Francis
The growing preference for producing cytochrome P450-mediated natural products in
microbial systems stems from the challenging nature of the organic chemistry approaches …

O2 sensitivity and H2 production activity of hydrogenases—A review

Y Lu, J Koo - Biotechnology and Bioengineering, 2019 - Wiley Online Library
Hydrogenases are metalloproteins capable of catalyzing the interconversion between
molecular hydrogen and protons and electrons. The iron–sulfur clusters within the enzyme …

[HTML][HTML] Selective oxyfunctionalisation reactions catalysed by P450 monooxygenases and peroxygenases–A bright future for sustainable chemical synthesis

X Xu, T Hilberath, F Hollmann - Current Opinion in Green and Sustainable …, 2023 - Elsevier
Heme-dependent oxygenases (ie P450 monooxygenases and peroxygenases) are highly
selective catalysts for the selective oxyfunctionalisation or organic compounds. Both enzyme …

[HTML][HTML] Rewiring cyanobacterial photosynthesis by the implementation of an oxygen-tolerant hydrogenase

S Lupacchini, J Appel, R Stauder, P Bolay, S Klähn… - Metabolic …, 2021 - Elsevier
Molecular hydrogen (H 2) is considered as an ideal energy carrier to replace fossil fuels in
future. Biotechnological H 2 production driven by oxygenic photosynthesis appears highly …

O2-tolerant [NiFe]-hydrogenases of Ralstonia eutropha H16: Physiology, molecular biology, purification, and biochemical analysis

O Lenz, L Lauterbach, S Frielingsdorf - Methods in enzymology, 2018 - Elsevier
Abstract Dioxygen-tolerant [NiFe]-hydrogenases are defined by their ability to catalyze the
reaction, H 2⇌ 2H++ 2e− even in the presence of O 2. Catalytic and probably also …