Trifluoromethylated aromatic compounds (Ar− CF3) are the substances of considerable
interest in various industrial fields. The high lipophilicity, strong electron‐withdrawing ability …

Herein, we report a Cu‐mediated trifluoromethylation of carbonyl‐type compounds and
unactivated olefins enabled by visible‐light irradiation via σ C (sp3)− C bond …

In spite of only a few naturally occurring products having one or more fluorine atoms,
organofluorine compounds have been widely utilized in pharmaceutical, agrochemical, and …

The synthesis, characterization, and reactivity of key intermediates [Cu (CF3)(X)]− Q+ (X=
CF3 or I, Q= PPh4) in copper-mediated trifluoromethylation of aryl halides were studied …

Comprehensive Summary Five‐coordinate neutral Cu (III) complexes have long been
considered as the key intermediates in copper‐mediated/catalyzed arene …

Efficient methods for labeling aryl trifluoromethyl groups to provide novel radiotracers for use
in biomedical research with positron emission tomography (PET) are keenly sought. We …

Cobalt (III) and cobalt (II) perfluoroethyl complexes supported by 1, 8-naphthyridine or its
mono-or dimethylsubstituted analogues were synthesized, and their reactivity has been …

A simple and straightforward approach to the synthesis of trifluoromethyl and difluoromethyl
ketones from widely available carboxylic acids is disclosed. The transformation utilizes an …

This review highlights the recent advances, from 2015 to 2023, on the introduction of organo-
fluorine derivatives at the N-heteroarene core. Notable features considering new …

Abstract α‐Trifluoromethyl alkenes are versatile CF3‐containing feedstocks. They have
been widely used to construct gem‐difluoroalkene scaffolds through β− F elimination. The …