Ammonia–borane and amine–borane dehydrogenation mediated by complex metal hydrides

A Rossin, M Peruzzini - Chemical reviews, 2016 - ACS Publications
This review is a comprehensive survey of the last 10 years of research on ammonia–borane
and amine–borane dehydrogenation mediated by complex metal hydrides (CMHs), within …

Amine‐Borane Dehydrogenation and Transfer Hydrogenation Catalyzed by α‐Diimine Cobaltates

TM Maier, S Sandl, IG Shenderovich… - … A European Journal, 2019 - Wiley Online Library
Anionic α‐diimine cobalt complexes, such as [K (thf) 1.5 {(DippBIAN) Co (η4‐cod)}](1; Dipp=
2, 6‐diisopropylphenyl, cod= 1, 5‐cyclooctadiene), catalyze the dehydrogenation of several …

Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular …

ES Gulyaeva, ES Osipova, SA Kovalenko… - Chemical …, 2024 - pubs.rsc.org
Metal–metal cooperation for inert bond activation is a ubiquitous concept in coordination
chemistry and catalysis. While the great majority of such transformations proceed via …

Cobalt-catalyzed ammonia borane dehydrogenation: Mechanistic insight and isolation of a cobalt hydride-amidoborane complex

JW Nugent, M García-Melchor, AR Fout - Organometallics, 2020 - ACS Publications
A Co (I) complex featuring the electron-rich monoanionic bis (carbene) aryl pincer ligand
(MesCCC)(MesCCC= bis (2, 4, 6-trimethylphenyl-benzimidazol-2-ylidene) …

Ammonia Borane Dehydrogenation Catalyzed by (κ4-EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids

S Todisco, L Luconi, G Giambastiani, A Rossin… - Inorganic …, 2017 - ACS Publications
Two Co (I) hydrides containing the tripodal polyphosphine ligand EP3,(κ4-EP3) Co (H)[E
(CH2CH2PPh2) 3; E= N (1), P (2)], have been exploited as ammonia borane (NH3BH3, AB) …

Catalysis and Mechanism of H2 Release from Amine-Boranes by Diiron Complexes

AM Lunsford, JH Blank, S Moncho, SC Haas… - Inorganic …, 2016 - ACS Publications
Studies focused on the dehydrogenation of amine-borane by diiron complexes that serve as
well-characterized rudimentary models of the diiron subsite in [FeFe]-hydrogenase are …

Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt (ii), Shimoi-type, η 1-BH complex

M Roselló-Merino, RJ Rama, J Díez… - Chemical …, 2016 - pubs.rsc.org
Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of
a Pt( ii ), Shimoi-type, η 1 -BH complex - Chemical Communications (RSC Publishing) DOI:10.1039/C6CC02720B …

A unified set of experimental organometallic data used to evaluate modern theoretical methods

RK Raju, AA Bengali, EN Brothers - Dalton Transactions, 2016 - pubs.rsc.org
We applied a test set of ligand dissociation enthalpies derived entirely from a unified
experimental approach to evaluate the efficacy of various methods for modeling …

A Highly Active Bidentate Magnesium Catalyst for Amine‐Borane Dehydrocoupling: Kinetic and Mechanistic Studies

ACA Ried, LJ Taylor, AM Geer… - … A European Journal, 2019 - Wiley Online Library
A magnesium complex (1) featuring a bidentate aminopyridinato ligand is a remarkably
selective catalyst for the dehydrocoupling of amine‐boranes. This reaction proceeds to …

Stereospecific Synthesis of α‐ and β‐Hydroxyalkyl P‐Stereogenic Phosphine–Boranes and Functionalized Derivatives: Evidence of the PO Activation in the BH3 …

S Lemouzy, DH Nguyen, V Camy… - … A European Journal, 2015 - Wiley Online Library
Access to hydroxy‐functionalized P‐chiral phosphine–boranes has become an important
field in the synthesis of P‐stereogenic compounds used as ligands in asymmetric catalysis …