Recent years have witnessed an increase in the popularity of α-boryl organometallic
reagents as versatile nucleophiles in asymmetric synthesis. These compounds have been …

A Pd-catalyzed enantioselective three-component reaction of N-sulfonylhydrazones, aryl
bromides, and silylboronic esters is developed, enabling the synthesis of chiral gem …

Geminal and vicinal borosilanes are useful building blocks in synthetic chemistry and
material science. Hydrosilylation/hydroborylation of unsaturated systems offer expedient …

The wide applications of alpha‐boryl carbanions in selective coupling with organohalides,
imines/carbonyls and conjugated unsaturated substrates has become an interesting tool for …

Chiral α-substituted allylboronic acids were synthesized by asymmetric homologation of
alkenylboronic acids using CF3/TMS-diazomethanes in the presence of BINOL catalyst and …

Described here is a simple and efficient method to prepare organoboron compounds
through α-deprotonation and functionalization of benzylboronates. In addition to alkyl …

A broad range of aliphatic, aromatic, and heterocyclic boronic acids were successfully
homologated using trifluorodiazoethane in the presence of BINOL derivatives to provide the …

Transition-metal-catalyzed Si–H bond insertion reactions are generally limited to stabilized
diazo compounds. An efficient copper-catalyzed Si–H bond insertion reaction of N-propargyl …

Gem-borylsilylalkanes are versatile intermediates in organic synthesis, and the traditional
synthesis methods have mainly focused on metal reagents, the insertion reactions of diazo …

Insertion reactions of carbenes or ylides with organoboronic acids or their derivatives have
emerged as valuable methods for coupling or homologation of organoboron compounds …