Impact of 3d Metal Ions on the Magnetic Dynamics in Isostructural Tetranuclear Butterfly {Ni2IIDy2III} and {Co2IIDy2III} Complexes

NC Jana, A Escuer, R Herchel, J Serra… - Crystal Growth & …, 2024 - ACS Publications
This paper describes the synthesis, structures, and magnetic properties of four isostructural
butterfly-type heterometallic tetranuclear 3d-4f complexes,[Ni2Dy2 (HL1) 2 (μ3–OH) 2 (piv) …

Inclusion of Ln(III) in the Complexes of Co(II) with a Mannich Base Ligand: Development of Atmospheric CO2 Fixation and Enhancement of Catalytic Oxidase …

A Das, S Goswami, R Sen, A Ghosh - Inorganic Chemistry, 2019 - ACS Publications
The reaction of the Mannich base ligand (H2L= N, N′-dimethyl-N, N′-bis (2-hydroxy-3-
methoxy-5-methylbenzyl) ethylenediamine) with Co (OAc) 2· 4H2O and Ln (III) nitrate salts …

Highly water-soluble dimeric and trimeric lanthanide carbonates with ethylenediaminetetraacetates as precursors of catalysts for the oxidative coupling reaction of …

RY Lin, YR Shi, YH Hou, WS Xia, WZ Weng… - New Journal of …, 2022 - pubs.rsc.org
Reactions of carbon dioxide with lanthanide ethylenediaminetetraacetates M [Ln
(EDTA)(H2O) 3]· 5H2O (M= NH4, Na or K; Ln= La or Ce) result in the formation of highly …

Highly water-soluble ternary citrato and malato lanthanide ethylenediaminetetraacetes with carbonate

YR Shi, RY Lin, ML Chen, X Dong, HY Li… - Journal of Molecular …, 2022 - Elsevier
Highly water-soluble dimeric lanthanum and cerium ethylenediaminetetraacetes with
carbonate K 8 [Ln 2 (CO 3)(Hcit)(EDTA) 2] Cl· 10.5 H 2 O [Ln= La, 1; Ce, 2] and K 6 [Ln 2 …

Lanthanide metal-organic frameworks containing ferromagnetically coupled metal-carboxylate chains showing slow magnetic relaxation behavior

LL Li, SS Chen, S Liu, ZH Yong, DK Zhang… - Journal of Molecular …, 2023 - Elsevier
Lanthanide metal-organic frameworks (Ln-MOFs) with slow magnetic relaxation behavior
are of great interest to scientists due to their rich and peculiar physical phenomena and spin …

Generalized Heisenberg-Type Magnetic Phenomena in Coordination Polymers with Nickel–Lanthanide Dinuclear Units

M Antkowiak, MC Majee, M Maity… - The Journal of …, 2021 - ACS Publications
A new family of 3d–4f coordination polymers with the molecular formula [NiIILnIII (L)(dca) 2
(NO3)] n [Ln= Eu (1), Gd (2), Tb (3), Dy (4), and Ho (5); H2L= N, N′-bis (2-hydroxy-3 …

Russian Doll-like 3d–4f Cluster Wheels with Slow Relaxation of Magnetization

L Liu, P Yang, Z Qiu, K Wang, D Liu, Y Liang, H Hu… - Molecules, 2023 - mdpi.com
The solvothermal reactions of LnCl3· 6H2O and MCl2· 6H2O (M= Co, Ni) with 2, 2′-
diphenol (H2L1) and 5, 7-dichloro-8-hydroxyquinoline (HL2) gave three 3d–4f …

Formation of a carbonato bridged Ni4-complex by atmospheric CO2 fixation: Crystal structure and magnetic properties

M Mondal, J Mayans, A Ghosh - Inorganica Chimica Acta, 2019 - Elsevier
Abstract Reaction of NiCl 2· 6H 2 O with a simple N 2 O donor tridentate reduced Schiff base
ligand, 2-[(3-methylamino-propylamino)-methyl]-4-nitro-phenol (HL) yielded a tetranuclear …

A series of linear CoII2LnIII2 clusters derived from 3, 4-dichlorobenzoate and 2, 2′-bipyridine: Syntheses, structures, and properties

JW Zhang, WH Liu, CR Wang, BQ Liu, YP Dong - Inorganica Chimica Acta, 2020 - Elsevier
The reactions of Co (NO 3) 2· 6H 2 O, Ln (NO 3) 3· nH 2 O, 3, 4-dichlorobenzoic acid (3, 4-
HDCB), 2, 2′-bipyridine (2, 2′-bpy), and NaOH under solvothermal conditions of H 2 O …

Two heterometallic {CoII6LnIII2} (Ln = Dy, Ho) clusters with local symmetry exhibiting single‐molecule magnet behaviours

X Zhao, T Zhao, Y Wang, J Zhou - Applied Organometallic …, 2023 - Wiley Online Library
Two novel 3d‐4f clusters with {CoII6LnIII2}(Ln= Dy (1), Ho (2)) cores are fabricated, with
formulas of {[Co6Ln2 (O) 2 (dhpb) 6 (NO3) 2 (DMF) 2]· H2O}(H2dhpb= 6, 6′‐dihydroxyl‐2 …