Energy, charge, and spin transport in molecules and self-assembled nanostructures inspired by photosynthesis

MR Wasielewski - The Journal of organic chemistry, 2006 - ACS Publications
Electron transfer in biological molecules provides both insight and inspiration for developing
chemical systems having similar functionality. Photosynthesis is an example of an integrated …

Tuning orbital energetics in arylene diimide semiconductors. Materials design for ambient stability of n-type charge transport

BA Jones, A Facchetti, MR Wasielewski… - Journal of the …, 2007 - ACS Publications
Structural and electronic criteria for ambient stability in n-type organic materials for organic
field-effect transistors (OFETs) are investigated by systematically varying LUMO energetics …

Energy flow dynamics within cofacial and slip-stacked perylene-3, 4-dicarboximide dimer models of π-aggregates

RJ Lindquist, KM Lefler, KE Brown… - Journal of the …, 2014 - ACS Publications
Robust perylene-3, 4-dicarboximide (PMI) π-aggregates provide important light-harvesting
and electron–hole pair generation advantages in organic photovoltaics and related …

Cyanated perylene-3, 4-dicarboximides and perylene-3, 4: 9, 10-bis (dicarboximide): Facile chromophoric oxidants for organic photonics and electronics

MJ Ahrens, MJ Fuller, MR Wasielewski - Chemistry of materials, 2003 - ACS Publications
Cyanated perylene-3, 4-dicarboximides and perylene-3, 4: 9, 10-bis (dicarboximide) s
absorb strongly in the visible spectrum and are strong oxidants. The stable radical anions of …

Beyond exciton theory: a time-dependent DFT and Franck− Condon study of perylene diimide and its chromophoric dimer

AE Clark, C Qin, ADQ Li - Journal of the American Chemical …, 2007 - ACS Publications
The diimide perylene motif exhibits a dramatic intensity reversal between the 0→ 0 and 0→
1 vibronic bands upon π− π stacking; this distinct spectral property has previously been …

A perspective on four new porphyrin-based functional materials and devices

CM Drain, JT Hupp, KS Suslick… - Journal of Porphyrins …, 2002 - World Scientific
The tremendous potential for the manifold applications of porphyrins, porphyrazines, and
phthalocyanines derives from their photophysical and electrochemical properties, their …

Coupled sensitizer–catalyst dyads: electron‐transfer reactions in a perylene–polyoxometalate conjugate

F Odobel, M Séverac, Y Pellegrin… - … A European Journal, 2009 - Wiley Online Library
Ultrafast discharge of a single‐electron capacitor: A variety of intramolecular electron‐
transfer reactions are apparent for polyoxometalates functionalized with covalently attached …

Toward an n-type molecular wire: Electron hopping within linearly linked perylenediimide oligomers

TM Wilson, MJ Tauber… - Journal of the American …, 2009 - ACS Publications
A series of linearly linked perylenediimide (PDI) dimers and trimers were synthesized in
which the PDI π systems are nearly orthogonal. These oligomers and several model …

Excited-State Metal-to-Ligand Charge Transfer Dynamics of a Ruthenium(II) Dye in Solution and Adsorbed on TiO2 Nanoparticles from Resonance Raman …

LCT Shoute, GR Loppnow - Journal of the American Chemical …, 2003 - ACS Publications
The dynamics of metal-to-ligand charge transfer (MLCT) in a cis-bis (4, 4 '-dicarboxy-2, 2 '-
bipyridine)-bis (isothiocyanato) ruthenium (II) dye (N3) are compared for the free dye in …

Stokes shift/emission efficiency trade-off in donor–acceptor perylenemonoimides for luminescent solar concentrators

R Turrisi, A Sanguineti, M Sassi, B Savoie… - Journal of Materials …, 2015 - pubs.rsc.org
Perylenediimides (PDIs) are among the best performing organic luminescent materials, both
in terms of emission efficiency and chemical and photochemical stability because of their …