Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …
properties that rival polyolefins are seen as future high demand materials for a variety of …
Metal‐Catalyzed Hydrophosphination
BT Novas, R Waterman - ChemCatChem, 2022 - Wiley Online Library
Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …
fine chemicals. One‐time use of phosphate resources has made sustainable use of …
Broken promises? On the continued challenges faced in catalytic hydrophosphination
S Lau, TM Hood, RL Webster - ACS catalysis, 2022 - ACS Publications
In this Perspective, we discuss what we perceive to be the continued challenges faced in
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …
Thermally Stable Ln (II) and Ca (II) Bis (benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C–C Multiple Bonds
AN Selikhov, GS Plankin, AV Cherkasov… - Inorganic …, 2019 - ACS Publications
A series of Ln (II) and Ca (II) bis (alkyl) complexes with bulky benzhydryl ligands,[(pt Bu-
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …
C6H4) 2CH] 2M (L n)(M= Sm, L= DME, n= 2 (1); M= Sm, Yb, Ca, L= TMEDA, n= 1 (2, 3, 4) …
A bench-stable copper photocatalyst for the rapid hydrophosphination of activated and unactivated alkenes
SG Dannenberg, R Waterman - Chemical Communications, 2020 - pubs.rsc.org
Cu (acac) 2 (1) is a highly active catalyst for the hydrophosphination of alkenes.
Photocatalytic conditions are critical, and provide high conversions with unactivated …
Photocatalytic conditions are critical, and provide high conversions with unactivated …
CaII, YbII and SmII Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio‐ and Chemoselective Consecutive Hydrophosphinations with PH …
IV Lapshin, IV Basalov, KA Lyssenko… - … A European Journal, 2019 - Wiley Online Library
The first example of intermolecular hydrophosphination of styrene, 2‐vinylpyridine and
phenylacetylene with PH3 catalyzed by bis‐(amido) complexes [(Me3Si) 2N] 2M (NHC) 2 …
phenylacetylene with PH3 catalyzed by bis‐(amido) complexes [(Me3Si) 2N] 2M (NHC) 2 …
Ln (ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes–promising catalysts for olefin hydrophosphination
IV Lapshin, AV Cherkasov, AF Asachenko… - Chemical …, 2020 - pubs.rsc.org
Ln( ii ) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising
catalysts for olefin hydrophosphination - Chemical Communications (RSC Publishing) …
catalysts for olefin hydrophosphination - Chemical Communications (RSC Publishing) …
Mechanism and Catalyst Design in Ru-Catalyzed Alkene Hydrophosphination
A thorough experimental examination of a series of half-sandwich Ru indenyl complexes
[Ru (η5-indenyl)(PPh2)(L)(PPh3)(L= PPh2H, CO, NCPh)] in the catalytic …
[Ru (η5-indenyl)(PPh2)(L)(PPh3)(L= PPh2H, CO, NCPh)] in the catalytic …
N-Heterocyclic Carbene-Coordinated M(II) (M = Yb, Sm, Ca) Bisamides: Expanding the Limits of Intermolecular Alkene Hydrophosphination
IV Lapshin, AV Cherkasov, KA Lyssenko… - Inorganic …, 2022 - ACS Publications
A series of NHC-stabilized amido compounds (NHC) n M [N (SiMe3) 2] 2 (M= Yb (II), Sm (II),
Ca (II); n= 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to …
Ca (II); n= 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to …
Divergent Mechanistic Pathways for Copper (I) Hydrophosphination Catalysis: Understanding That Allows for Diastereoselective Hydrophosphination of a Tri …
SG Dannenberg, DM Seth Jr, EJ Finfer… - ACS …, 2022 - ACS Publications
Readily available and bench-stable Cu (acac) 2 (1) addresses many challenges in
exploratory hydrophosphination catalysis. Mechanistic investigations were performed to …
exploratory hydrophosphination catalysis. Mechanistic investigations were performed to …