Palladium-Catalyzed C(sp3)H Oxygenation via Electrochemical Oxidation

QL Yang, YQ Li, C Ma, P Fang… - Journal of the American …, 2017 - ACS Publications
Palladium-catalyzed C H activation/C O bond-forming reactions have emerged as
attractive tools for organic synthesis. Typically, these reactions require strong chemical …

Recent advances on palladium radical involved reactions

Q Liu, X Dong, J Li, J Xiao, Y Dong, H Liu - ACS Catalysis, 2015 - ACS Publications
Transformations involving Pd (I) and Pd (III) have received growing attention over the past
few years, providing various methodologies for the construction of numerous carbocyclic …

Catalytic Applications of Pyridine‐Containing Macrocyclic Complexes

G Tseberlidis, D Intrieri, A Caselli - European Journal of …, 2017 - Wiley Online Library
The introduction of a pyridine moiety into the skeleton of a polyazamacrocyclic ligand affects
both the thermodynamic properties and the coordination kinetics of the resulting metal …

Palladium-catalyzed C–H activation/C–C cross-coupling reactions via electrochemistry

C Ma, CQ Zhao, YQ Li, LP Zhang, XT Xu… - Chemical …, 2017 - pubs.rsc.org
Palladium-catalyzed C–H activation/C–C cross-coupling reactions typically require
stoichiometric chemical oxidants and exogenous ligands. However, there are significant …

Synthesis of Well‐Defined High‐Valent Palladium Complexes by Oxidation of Their Palladium (II) Precursors

B Zhang, X Yan, S Guo - Chemistry–A European Journal, 2020 - Wiley Online Library
The last decade has witnessed the rapid development of high‐valent Pd‐involved organic
transformations. This has also led to a steadily growing number of publications concerning …

Experimental and computational studies of high-valent nickel and palladium complexes

NM Camasso, AJ Canty, A Ariafard… - Organometallics, 2017 - ACS Publications
This article describes a detailed comparison of the organometallic chemistry of high-valent
nickel and palladium model complexes supported by tris (pyrazolyl) borate and …

Electrocatalytic H 2 evolution promoted by a bioinspired (N2S2) Ni (ii) complex

S Sinha, GN Tran, H Na, LM Mirica - Chemical Communications, 2022 - pubs.rsc.org
A bioinspired (N2S2) Ni (II) electrocatalyst is reported that produces H2 from CF3CO2H with
a turnover frequency (TOF) of∼ 1250 s− 1 at low acid concentration (< 0.043 M) in MeCN. A …

Detection and characterization of mononuclear Pd (I) complexes supported by N2S2 and N4 tetradentate ligands

J Luo, GN Tran, NP Rath, LM Mirica - Inorganic Chemistry, 2020 - ACS Publications
Palladium is a versatile transition metal used to catalyze a large number of chemical
transformations, largely due to its ability to access various oxidation states (0, I, II, III, and IV) …

Palladium K-edge X-ray Absorption Spectroscopy Studies on Controlled Ligand Systems

LP Westawker, JK Khusnutdinova, RF Wallick… - Inorganic …, 2023 - ACS Publications
X-ray absorption spectroscopy (XAS) is widely used across the life and physical sciences to
identify the electronic properties and structure surrounding a specific element. XAS is less …

Palladium‐catalyzed distal C− H selenylation of 2‐aryl acetamides with diselenides and selenyl chlorides

M He, L Gu, Y Tan, Y Wang, Y Wang… - Advanced Synthesis …, 2020 - Wiley Online Library
A convenient and effective method of palladium‐catalyzed C− H selenylation of the 2‐aryl
acetamides assisted with removable 8‐aminoquinoline with readily available diselenides …