Significance of the connecting position between Zn (ii) porphyrin and Re (i) bipyridine tricarbonyl complex units in dyads for room-temperature phosphorescence and …

Y Kuramochi, Y Suzuki, S Asai, T Suzuki, H Iwama… - Chemical …, 2023 - pubs.rsc.org
We synthesized three new dyads composed of a Zn porphyrin and fac-Re (bpy)(CO) 3Br
(bpy= 2, 2′-bipyridine) units, ZnP-nBpyReBr (n= 4, 5, and 6), in which the porphyrin is …

Electrochemical CO2 Reduction Catalytic Activity and Materials Characterization of Heterogeneous Zinc Carbonaceous Layers Derived from a Zinc(II) Molecular …

F Nkurunziza, CA Phipps, DT Hofsommer… - ACS Applied Energy …, 2023 - ACS Publications
Homogeneous molecular electrocatalysts have shown promise as a highly tailorable
platform for designing active sites with high selectivity for target products. However, many …

Enhancing CO2 Capture via Metal–Ligand Cooperativity: Tuning Ligand Basicity and Zn(II) Lewis Acidity

CA Phipps, CD Zirilli, BG Duff, JD Erickson… - Inorganic …, 2024 - ACS Publications
A series of thiosemicarbazonato-hydrazinatopyridine zinc (II) complexes were evaluated as
direct air CO2 capture agents. The complexes sequester CO2 in a methanol solution as a …

Syntheses and exploration of the catalytic activities of organotin (iv) compounds

M Kumar, HP Nayek - Dalton Transactions, 2024 - pubs.rsc.org
Six organotin (IV) compounds (1–6) have been synthesized by reaction of the polydentate
pro-ligands H3L and H2L, respectively, with the corresponding diorganotin chlorides. All of …

Reversible Capture Mechanism of CO2 as a Zn(II)‐Methylcarbonate

F Murillo, X Zarate, MA Fernández‐Herrera… - …, 2024 - Wiley Online Library
In this study, we elucidate the reaction mechanism for capturing CO2 with the ZnL1 (MeOH)
complex (L1= diacetyl‐2‐(4‐methyl‐3‐thiosemicarbazone)‐3‐(2‐hydrazinatopyridine)) in a …

Utilizing metal ligand cooperativity to activate small molecules.

C Burgan - 2024 - ir.library.louisville.edu
The problems created from the excessive use of fossil fuels can be approached from two
directions: capture the CO 2 from the atmosphere or develop alternative energy sources …

[引用][C] rsc. li/chemical-science

Y Kuramochi, MS Asano, A Satake - 2023 - pubs.rsc.org