Cyclic monomers bearing either vinyl or exomethylene groups have the ability to be
polymerized through a radical pathway via a ring-opening mechanism (addition …

This review covers the addition of diazo compounds to ketones to afford homologated
ketones, either in the presence or in the absence of promoters or catalysts. Reactions with …

Sulfoximines are increasingly incorporated in agrochemicals and pharmaceuticals, with the
two enantiomers of chiral sulfoximines often having profoundly different binding interactions …

From its earliest observation as an unusual reaction only a half century ago, 1 the insertion
of a carbene into a carbonrhydrogen bond has attracted considerable interest because of its …

In this tutorial review, recent advances in the synthesis of cyclopropane-containing natural
products are discussed, highlighting the application of novel synthetic methodologies and …

Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

The importance of chirality is well recognised, mainly in connection with the fact that nearly
all natural products are chiral and their physiological or pharmacological properties depend …

1. INTRODUCTION The catalysis of organic reactions by metals still constitutes one of the
most useful and powerful tools in organic synthesis. 1 Although asymmetric synthesis is …

A monoprotected aminoethyl amine chiral ligand based on an ethylenediamine backbone
was developed to achieve Pd-catalyzed enantioselective C (sp3)–H arylation of …