Recent advances in the (3+ 2) cycloaddition of azomethine ylide

S Dubey, A Pal, S Roy, S Sasmal, A Tamrakar… - New Journal of …, 2023 - pubs.rsc.org
Nitrogen-containing heterocyclic compounds are some of the most significant compounds
that are produced artificially or naturally. These heterocyclic rings are virtually always …

Recent Advances in Squaramide‐Catalyzed Asymmetric Mannich Reactions

XQ Hou, DM Du - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Bifunctional squaramides as a branch of organo‐catalysts showed powerful strategies in the
art of asymmetric synthesis, and they have been proved to be highly efficient and versatile …

DMAP Catalyzed Ring-Opening/Cycloaddition of Vinyl Oxiranes with Activated Ketone Compounds to Construct the 1, 3-Dioxolane Skeletons

J Qu, T Yang, X Zhao, C Sun, C Yuan, H Guo… - Organic …, 2024 - ACS Publications
The present work develops a DMAP-catalyzed [3+ 2] cycloaddition of vinyl oxiranes with
activated ketone compounds, affording dioxolane derivatives with moderate to excellent …

Construction of nine-membered N, N, O-heterocycles via Pd-catalyzed [6+ 3] dipolar cycloaddition

H Xie, Z Yang, L Tang, Z Han, J Sun… - Chemical …, 2022 - pubs.rsc.org
A new approach for the synthesis of 9-membered N, N, O-heterocycles by Pd-catalyzed [6+
3] dipolar cycloaddition of N-iminoisoquinolinium ylides and 2-vinyl oxetanes has been …

Phosphine-Catalyzed Tandem Annulation of Allenylic Alcohols with 1, 1-Dicyanoalkenes

Z Duan, M Liu, B Zheng, Y Tang, J Du, L Wang… - Organic …, 2023 - ACS Publications
The phosphine-catalyzed tandem annulation of allenylic alcohols with 1, 1-dicyanoalkenes
has been developed, giving various bicyclic tetrahydrocyclopentafuran derivatives in 40 …

Substrate-Controlled Diversity-Oriented Synthesis of Novel Polycyclic Frameworks via [4+ 2] and [3+ 2] Annulations of Ninhydrin-Derived MBH Adducts with 3, 4 …

K Wang, W Zhou, J Jia, J Ye, M Yuan, J Yang, Y Qi… - Molecules, 2023 - mdpi.com
Substrate-controlled diversity-oriented synthesis of polycyclic frameworks via [4+ 2] and [3+
2] annulations between ninhydrin-derived Morita–Baylis–Hillman (MBH) adducts and 3, 4 …

Phosphine-Catalyzed (4+ 2) Annulation of Allenoates Bearing Acidic Hydrogen with 1, 1-Dicyanoalkenes

Z Gao, X Zhou, L Xie, X Wang, S Wang… - The Journal of …, 2024 - ACS Publications
α-succinimide-substituted allenoates were employed as phosphine acceptors in phosphine-
catalyzed (4+ 2) annulation with 1, 1-dicyanoalkenes. They served as C4 synthons in the …

Palladium-catalyzed [5+ 2] annulation of vinylethylene carbonates with barbiturate-derived alkenes

X Gao, D Zhu, Y Chen, H Deng, F Jiang, W Wang… - Organic …, 2020 - ACS Publications
A palladium/XantPhos-catalyzed [5+ 2] annulation of VECs with electron-deficient alkenes
having an isolated carbon–carbon double bond has been developed to afford …

Phosphine-catalyzed cascade annulation of MBH carbonates and diazenes: Synthesis of hexahydrocyclopenta [c] pyrazole derivatives

H Li, W Shi, C Wang, H Liu, W Wang, Y Wu… - Organic Letters, 2021 - ACS Publications
A phosphine-catalyzed cascade annulation of Morita–Baylis–Hillman (MBH) carbonates and
diazenes was achieved, giving tetrahydropyrazole-fused heterocycles bearing two five …

Phosphine-catalyzed (4+ 2) annulation of δ-sulfonamido-substituted enones with 1, 1-dicyanoalkenes: synthesis of piperidine derivatives

M Liu, L Zhou, W Shi, Y Hu, J Liao, Z Duan… - Organic …, 2021 - ACS Publications
The δ-sulfonamido-substituted enones were employed as phosphine acceptor in phosphine-
catalyzed (4+ 2) annulation of 1, 1-dicyanoalkenes. They served as a four-membered …