Nickel‐and palladium‐catalyzed insertion copolymerization of ethylene and acrylate
comonomers for synthesis of ethylene‐acrylates copolymers have attracted much academic …

Studies on transition-metal catalyzed olefin-polar monomer coordination copolymerization
and their resulting polar-functionalized polyolefin materials have attracted attention from …

Polar monomer-induced β-H elimination is a key elementary step in polar polyolefin
synthesis by coordination polymerization but remains underexplored. Herein, we show that …

Recent breakthroughs in the generation of polar-functionalized and more sustainable
degradable polyethylenes have been enabled by advanced phosphinephenolato Ni (II) …

Recently, phosphorus phenol nickel catalysts have attracted widespread attention from the
academic community due to their excellent copolymerization performance. Here, a series of …

Rapid, efficient development of homogeneous catalysts featuring desired performance is
critical to numerous catalytic transformations but remains a key challenge. Typically, this task …

Defect engineering has developed over the last decade to become an inimitable tool with
which to shape Metal-Organic Framework (MOF) chemistry; part of an evolution in the …

Hydrocarbons, when used as the medium for transition metal catalyzed organic reactions
and olefin (co‐) polymerization, are ubiquitous. Environmentally friendly water is highly …

In catalytic olefin polymerization, a significant amount of effort has been invested to modify
either phosphine substituent or ligand backbone in recently advanced phosphine-phenolate …

Our previous research established the benefits of axially flexible substituents in α-diimine-
catalyzed ethylene polymerization, noting their role in enhancing polyethylene branching. In …