Unlike natural macromolecules (eg, nucleic acids and proteins) possessing precisely
defined molar mass, chain sequence, chirality, and topology, synthetic polymers are typically …

Natural macromolecules, such as proteins and nucleic acids, display various complex
functionalities in biological systems. These functionalities depend on the macromolecular …

Healable silicone materials have great technical impact in coatings, smart actuators, and
flexible electronics, however, current healable silicone materials lack mechanical tunability …

In the last decade, the field of sequence‐defined polymers and related ultraprecise,
monodisperse synthetic macromolecules has grown exponentially. In the early stage, mainly …

Precise oligomeric materials constitute a growing area of research with implications for
various applications as well as fundamental studies. Notably, this field of science which can …

Molecular shape is an essential parameter that regulates the self-organization and
recognition process, which has not yet been well appreciated and exploited in block …

Many synthetic polymers used to form polymer-brush films feature a main backbone with
functional, oligomeric side chains. While the structure of such graft polymers mimics …

We report a comprehensive understanding of the stereoselective interaction between two
opposite enantiomeric polyesters prepared from the regioselective copolymerization of …

Conformational asymmetry of block copolymers is a critical molecular parameter dictating
the self-assembly behaviors. This work develops an efficient approach to construct block …

The graft‐through synthesis of Janus graft block copolymers (GBCPs) from branched
macromonomers composed of various combinations of homopolymers is presented. Self …