Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …

In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical
Reviews in 1998, no contribution was devoted to theory. This is not surprising because …

Polyoxometalates (POMs) as inorganic polyanionic clusters with abundant structural
fashions at the nanometer level display diverse applications in aspects of chemistry …

Oxidovanadium complexes and, to a less extent, some non-oxido ones, are widely used as
catalysts or catalyst precursors for various oxidative catalytic reactions by H 2 O 2, t BuOOH …

Vanadium compounds have attracted much attention because they have widely been used
for homogeneous, heterogeneous, industrial, and biological oxidation processes with alkyl …

The first example of a heterogeneous iron (III)‐catalyzed aerobic oxidation of aldehydes in
water was developed. This method utilizes 1 atmosphere of oxygen as the sole oxidant …

Direct functionalization of alkanes by oxidation of C–H bonds to form alcohols under mild
conditions is a challenge for synthetic chemistry. Most alkanes contain a large number of C …

Vanadium complexes have proven to be effective catalysts for the activation of peroxides
and the selective oxidation of substrates like bromides, sulfides and alkenes. Besides their …

The oxidation of alkenes by H2O2 catalyzed by Ti (IV)-containing polyoxometalates (POMs)
as models of Ti single-site catalysts has been investigated at DFT level and has been …

The epoxidation of olefins catalyzed by molecular transition metal compounds is a research
field, which has been extensively studied over the past forty years. To date, numerous types …